/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Q.49 What alkyl chloride affords the ... [FREE SOLUTION] | 91影视

91影视

Log out

Learning Materials

Features

Discover

Chapter 8: Q.49 (page 328)

What alkyl chloride affords the following alkene exclusively under E2 reaction conditions?

Short Answer

Expert verified

The alkyl chloride forms the mentioned alkene is shown below:

Step by step solution

01

Identification of the substrate

The primary halides always favor E2 reactions, whereas the secondary and tertiary halides favor E1 and E2, both depending on the bases used.

So to make the product exclusively an E2 product, a bulky base like potassium-tert-butoxide is used, which takes up a 尾 proton from the less hindered carbon.

02

Different types of β hydrogens

Different types of 尾hydrogens give different types of elimination products. Here only one type of 尾hydrogen is present, so it gives only one product.

So, taking into account all the steps and the types of 尾hydrogens present, the possible alkyl halide which undergoes E2 reaction is as follows:

Representation of E2 reaction

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91影视!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Rank the alkyl halides in each group in order of increasing reactivity in an E2 reaction.

a.

b.

Given that an E2 reaction proceeds with anti periplanar stereochemistry, draw the products of each elimination. The alkyl halides in (a) and (b) are diastereomers of each other. How are the products of these two reactions related? Recall from Section 3.2A that -C6H5is a phenyl group, a benzene ring bonded to another group.

a.

b.

Draw an E1 mechanism for the following reaction. Draw the structure of the transition state for each step.

Draw a stepwise mechanism for the following reaction.

鈭咹掳values obtained for a series of similar reactions are one set of experimental data used to determine the relative stability of alkenes. Explain how the following data suggest that cis-but-2-ene is more stable than but-1-ene (Section 12.3A).
See all solutions

Recommended explanations on Chemistry Textbooks

The Earths Atmosphere

Read Explanation

Kinetics

Read Explanation

Physical Chemistry

Read Explanation

Chemical Reactions

Read Explanation

Nuclear Chemistry

Read Explanation

Organic Chemistry

Read Explanation
View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.