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Chapter 4: Q.6. (page 128)

Question: Draw the five constitutional isomers that have molecular formula C5H10and contain one ring.

Short Answer

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Answer

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01

Constitutional isomers

A constitutional isomer can be represented by a cyclic ring or linear structure, depending on its molecular formula. Such isomers have different bonding atoms.

02

Cycloalkane

Acycloalkane has the general molecular formula CnH2n, where n is the number of carbon atoms.

03

Explanation

The given molecule, C5H10, has five carbon atoms and ten hydrogen atoms. The isomers are represented below.

Isomers of C5H10

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Most popular questions from this chapter

Question: Cyclopropane and cyclobutane have similar strain energy despite the fact that the C-C-C bond angles of cyclopropane are much smaller than those of cyclobutane. Suggest an explanation for this observation, considering all sources of strain discussed in Chapter 4.

Question: The torsional energy in propane is 14 kJ/mol (3.4 kcal/mol). Because each H,H eclipsing interaction is worth 4.0 kJ/mol (1.0 kcal/mol) of destabilization, how much is one H, CH3 eclipsing interaction worth in destabilization? (See Section 4.10 for an alternate way to arrive at this value.)

Question: Draw both conformations for 1-ethyl-1-methylcyclohexane and decide which conformation (if any) is more stable.

Question: Give IUPAC name of each compound.

a.

b.

c.

d.

Question: Consider the tricyclic structure B.

(a) Label each substituent on the rings as axial or equatorial.

(b) Draw B using chair conformations for each six-membered ring.

(c) Label the atoms on the ring fusions (the carbons that join each set of two rings together) as cis or trans to each other.

B
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