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Chapter 9: Q30. (page 365)

Question: Name each thiol.

a.

b.

Short Answer

Expert verified

Answer

a. 4-ethyl-2-methylhexane-1-thiol

b. 4,6-dimethyloctane-2-thiol

Step by step solution

01

Step-by-Step Solution Step 1: IUPAC of thiol

The function group used to represent thiol is 鈥揝H. The first step is to find out the longest chain of the compound. The suffix used for 鈥揝H group is a thiol.

02

Naming of the thiol of a

a. The given compound contains the 鈥揝H group. It is composed of six carbon atoms in a chain in which the thiol group, the methyl group, and an ethyl group are attached to C-1, C-2, and C-3 atoms, respectively.

The name of the thiol is 4-ethyl-2-methylhexane-1-thiol, as shown below.

4-ethyl-2-methylhexane-1-thiol

03

Naming of the thiol of b

b. The given compound contains the 鈥揝H group. It is composed of eight carbon atoms in a chain in which the thiol group and two methyl groups are attached to C-2, C-4, and C-6 atoms, respectively.

The name of the thiol is 4,6-dimethyloctane-2-thiol, as shown below.

4,6-dimethyloctane-2-thiol

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Most popular questions from this chapter

Question:(a) What reaction conditions are needed to convert (R)-2-ethyl-2-methyloxirane to (R)-2-methylbutane-1,2-diol?

(b) What reaction conditions are needed to convert (R)-2-ethyl-2-methyloxirane to (S)-2-methylbutane-1,2-diol?

Question: Draw a stepwise, detailed mechanism for the following intramolecular reaction that forms a cyclic ether.

Question: Label each ether and alcohol in Brevenal, a marine natural product. Classify each alcohol as1掳,2掳,3掳

Question: Draw the substitution product formed (including stereochemistry) when (R)-hexan-2-ol is treated with each series of reagents: (a) NaH, followed by CH3I ; (b) TsCl and pyridine, followed by NaOCH3 ; (c) PBr3, followed by NaOCH3. Which two routes produce identical products?

Question: Draw the product of each reaction, indicating the stereochemistry at any stereogenic center.

b.

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