Chapter 13: Q 57P (page 419)
Question: The NMR spectra of compound A, , are shown. Propose a structure for A, and assign peaks in the spectra to your structure.


Short Answer

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Chapter 13: Q 57P (page 419)
Question: The NMR spectra of compound A, , are shown. Propose a structure for A, and assign peaks in the spectra to your structure.



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How many types of non-equivalent protons are present in each of the following molecules?

How many absorptions would you expect to observe in the NMR
spectra of the following compounds?
(a) 1,1-Dimethylcyclohexane
(b) CH3CH2OCH3
(c) tert-Butylcyclohexane
(d) 3-Methyl-1-pentyne
(e) cis-1,2-Dimethylcyclohexane
(f) Cyclohexanone
The proton NMR spectrum is shown for a compound with the formula . The infrared spectrum displays strong bands at 1750 and 1562 and a medium-intensity band at 1320 . The normal carbon-13 and the DEPT experimental results are tabulated. Draw the structure of this compound.

Suppose you ran a DEPT-135 spectrum for each substance in Problem
13-47. Which carbon atoms in each molecule would show positive
peaks, and which would show negative peaks?
The proton NMR spectrum of a compound with the formula C5H10O isshown. The normal carbon-13 and the DEPT experimental results aretabulated. The infrared spectrum shows a broad peak at about3340 cm-1 and a medium-sized peak at about 1651 cm-1. Draw the structure of thiscompound.

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