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Chapter 12: Q1P (page 354)

Predict the aldol reaction product of the following compounds:

Short Answer

Expert verified

Aldehydes and ketones with a hydrogen atom undergo a base-catalyzed carbonyl condensation reaction called the aldol reaction.

An aldol reaction combines two molecules of the reactant by forming a bond between the carbon of one partner and the carbonyl carbon of the second partner. The product is a b-hydroxy aldehyde or ketone, meaning that the two oxygen atoms in the product have a 1,3 relationship.

Step by step solution

01

Step 1:

Aldehydes and ketones with a hydrogen atom undergo a base-catalyzed carbonyl condensation reaction called the aldol reaction.

02

Step 2: (a)mechanism of aldol reaction is

03

(b)Product of the second reactant is:

04

(c)Product of the third reactant is:

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Most popular questions from this chapter

Question: Grignard reagents undergo a general and very useful reaction with

ketones. Methylmagnesium bromide, for example, reacts with cyclohexanoneto yield a product with the formulaC7H14O . What is the structure of this product if it has an IR absorption at 3400cm-1?

Name the following alkynes, and predict the products of their reaction

With:

(1) H2in the presence of a Lindlar鈥檚 catalyst

(2) H3O+in the presence of H2SO4

Draw and name the following

a) The eight carboxylic acids with the formula C6H12O2

b) Three nitriles with the formula C5H7N

The infrared spectrum of the compound with the mass spectrum shown below lacks any significant absorption above 3000cm-1 . There is a prominent peak near 1740cm-1 and another strong peak near 1200cm-1 .

Propose a structure consistent with the data.

Question: Show the structures of the fragments you would expect in the mass spectra of the following molecules:
See all solutions

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