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Chapter 3: Q16 P-c. (page 85)

Sight along the C2-C1 bond of 2-methylpropane (isobutane).

(c) Make a graph of energy versus angle of rotation around the C2-C1 bond.

Short Answer

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(c)

Step by step solution

01

Graph of energy versus angle of rotation

The eclipsed conformation is less stable than the staggered conformation. This is because it comprises more potential energy due to the torsional strain.

02

Graph of energy versus angle of rotation around the C2-C1 bond

(c) A particular molecule鈥檚 stability is inversely related to its energy. Hence, the atom possessing less energy is more stable. The atom with high energy is least stable. The graph of energy versus the angle of rotation can be given as:

Graph of energy versus angle of rotation

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Most popular questions from this chapter

Draw a Newman projection along the C2-C3 bond of the following conformation of 2-butanol.

Increased substitution around a bond leads to increased strain. Take the four substituted butanes listed below, for example. For each compound, sight along the C2鈥揅3 bond and draw Newman projections of the most stable and least stable conformations. Use the data in Table 3-5 to assign strain-energy values to each conformation. Which of the eight conformations is most strained? Which is least strained?

(a) 2-Methylbutane

(b) 2,2-Dimethylbutane

(c) 2,3-Dimethylbutane

(d) 2,2,3-Trimethylbutane

In the next chapter we鈥檒l look at cycloalkanes鈥攕aturated cyclic hydrocarbons鈥攁nd we鈥檒l see that the molecules generally adopt puckered, nonplanar conformations. Cyclohexane, for instance, has a puckered shape like a lounge chair rather than a flat shape. Why?

Give IUPAC names for the following alkanes, and convert each drawing

into a skeletal structure.

How many isomers are there with the following descriptions?

(b) Bromoalkanes with the formulaC4H9Br
See all solutions

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