Chapter 9: 9-56a (page 286)
Which of the following bases could be used to deprotonate 1-butyne?
(a)
Short Answer
KOH will not deprotonate 1-butyne
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Chapter 9: 9-56a (page 286)
Which of the following bases could be used to deprotonate 1-butyne?
(a)
KOH will not deprotonate 1-butyne
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A cumulene is a compound with three adjacent double bonds. Draw an orbital picture of a cumulene. What kind of hybridization do the two central carbon atoms have? What is the geometric relationship of the substituents on one end to the substituents on the other end? What kind of isomerism is possible? Make a model to help see the answer.
A cumulene
The pkaof acetone, , is 19.3. Which of the following bases is strong enough to deprotonate acetone?
(c) (of H2CO36.4)
How would you prepare cis-2-butene starting from propyne, an alkyl halide, and any other reagents needed? This problem can’t be worked in a single step. You’ll have to carry out more than one reaction.
Occasionally, a chemist might need to invert the stereochemistry of an alkene—that is, to convert a cis alkene to a trans alkene, or vice versa. There is no one-step method for doing an alkene inversion, but the transformation can be carried out by combining several reactions in the proper sequence. How would you carry out the following reactions?
(a)
(b)
There are seven isomeric alkynes with the formula . Draw and name them.
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