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Chapter 7: Q44E (page 219)

Q 44Draw and name the 17 alkene isomers,C6H12 , including E, Z isomers.

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01

Definition of Isomers and degree of unsaturation

Isomers are those compounds which have same molecular formula but different structure. These compounds termed as Isomers

Degree of unsaturation is defined as total number of multiple bonds present in the compounds

Degree of unsaturation =C-H2-X2+N2+1

02

Structure of possible alkene

Degree of unsaturation for C6H12 = 1

Structure of the alkene has been drawn on the basis of same molecular formula with different structures

Structure of all the possible alkene has been given below:

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Most popular questions from this chapter

Draw structures corresponding to the following systematic names:

(a)(4E)-2, 4-Dimethyl-1, 4-hexadiene

(b)cis-3, 3-Dimethyl-4-propyl-1, 5-octadiene

(c)4-Methyl-1, 2-pentadiene

(d)(3E,5Z)-2, 6-Dimethyl-1, 3, 5,7-octatetraene

(e)3-Butyl-2-heptene

(f)trans-2, 2, 5, 5-Tetramethyl-3-hexene

Draw a skeletal structure of the following carbocation. Identify it as primary, secondary, or tertiary, and identify the hydrogen atoms that have the proper orientation for hyperconjugation in the conformation shown.

Question : Trans-2-Butene is more stable than cis-2-butene by only 4 kJ/mol, but trans-2,2,5,5-tetramethyl-3-hexene is more stable than its cis isomer by 39 kJ/mol. Explain.

Aromatic compounds such as benzene react with alkyl chlorides in the presence ofAlCl3catalyst to yield alkylbenzenes. This reaction occurs through a carbocation intermediate, formed by reaction of the alkyl chloride withAlCl3.(R-Cl+AlCl3鈫�R++AlCl4-)How can you explain the observation that reaction of benzene with 1-chloropropane yields isopropylbenzene as the major product?

Question: Addition of HCl to 1-isopropylcyclohexene yields a rearranged product.

Propose a mechanism, showing the structures of the intermediates and using curved arrows to indicate electron flow in each step
See all solutions

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