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Chapter 6: Q20P (page 255)

What will be the product of the preceding reaction if HBr is used in place of Br2?

Short Answer

Expert verified

Addition of H+ will form a carbocation that could rearrange.

Step by step solution

01

Addition of H+-

Addition of H+ will form a carbocation that could rearrange.

02

Addition of Br-- 

Addition of Br- forms a cyclic bromonium ion rather than a carbocation, so there is no rearrangement.

03

Conclusion-

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Most popular questions from this chapter

a. What alkene would give only a ketone with three carbons as a product of oxidative cleavage?

b. What alkenes would give only an aldehyde with four carbons as a product of oxidative cleavage?

What stereoisomers are obtained from hydroboration鈥搊xidation of the following compounds?Assign an Ror Sconfiguration to each asymmetric center.

a. cyclohexene c. cis-2-butene

b. 1-ethylcyclohexene d. (Z)-3,4-dimethyl-3-hexene

:a. How does the first step in the reaction of propene with Br2 differ from the first step in the reaction of propene with HBr?

b. To understand why Br- adds to a carbon of the bromonium ion rather than to the positively charged bromine, draw the product that would be obtained if Br- did add to bromine.

What stereoisomers would you expect to obtain from each of the following reactions

Give two names for each of the following:
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