/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Q13 P Which compound is more easily de... [FREE SOLUTION] | 91影视

91影视

Log out

Learning Materials

Features

Discover

Chapter 23: Q13 P (page 1085)

Which compound is more easily decarboxylated?

Short Answer

Expert verified

Compound 2 is much easier to decarboxylate than compound 1 because of resonance.

Step by step solution

01

Resonance

Resonance is the phenomenon of delocalization of pi-electron in a structure. Resonance provides more stability to a molecule.

02

Stability of compound 1

The first compoundis given below here it can be seen that on elimination the electron left behind are not present in resonance and are localized on carbon which is less electronegative atom and hence this makes the decarboxylation difficult to occur

Compound 1

03

Stability of compound 2

The second compoundis given below here it can be seen that on elimination the electron left behind are delocalized to positively charged nitrogen in ring by resonance and nitrogen is highly electronegative atom and hence this makes the decarboxylation easy to occur.

Compound 2

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91影视!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Question: How do the structures of tetrahydrofolate and aminopterin differ?

How many conjugated double bonds are there in

a. FAD?

b. FADH2

Question:When UMP is dissolved in T2O, exchange of T for H occurs at the 5-position. Propose a mechanism for this exchange.

Draw structures that show the similarity between the decarboxylation of the pyruvate鈥揟PP intermediate and the decarboxylation of a \(\beta \)-keto acid.

Explain why the ability of PLP to catalyze an amino acid transformation is greatly reduced if a PLP- requiring enzymatic reaction is carried out at a pH at which the pyridine nitrogen is not protonated.
See all solutions

Recommended explanations on Chemistry Textbooks

Ionic and Molecular Compounds

Read Explanation

Chemistry Branches

Read Explanation

Nuclear Chemistry

Read Explanation

Chemical Reactions

Read Explanation

Organic Chemistry

Read Explanation

Physical Chemistry

Read Explanation
View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.