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Chapter 15: Q87P (page 737)

Question: What product do you expect to obtain from each of the following reactions?

a.

b.

Short Answer

Expert verified

Answer

a.

b.

Step by step solution

01

Identification of product in first reaction (a)

. The reaction of 5-hydroxyheptanoic acid with hydrochloric acid is given below

Reaction (a)

This product is named6-ethyloxan-2-one. In this chemical reaction, when hydrochloric acid reacts with 5-hydroxyheptanoic acid, cyclisation occurs with the removal of water molecule.

02

Finding the product in second reaction (b)

The reaction of ethyl (hydroxymethyl)cyclopentyl]acetate with hydrochloric acid is given below.

Reaction (b)

This product is named hexahydrocyclopenta[c]pyran--one.

In this chemical reaction,cyclisation occurs with the release of ethanol.

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Most popular questions from this chapter

Which alkyl halides form the carboxylic acids listed hereafter reaction with sodium cyanide followed by heating the product in an acidic aqueous solution?

a. butyric acid

b. isovaleric acid

c. cyclohexane carboxylic acid

Question: Draw a structure for each of the following:

a. N,N-dimethylhexanamide

b. 3,3-dimethylhexanamide

c. Cyclohexanecarbonyl chloride

d. Propanenitrile

e. propionamide

f. sodium acetate

g. benzoic anhydride

h. b-valerolactone

i. 3-methylbutanenitrile

j. cycloheptanecarboxylic acid

k. benzoyl chloride

Primary amines can also be prepared by the reaction of an alkyl halide with azide ion, followed by catalytic hydrogenation. What advantage do this method and the Gabriel synthesis have over the synthesis of a primary amine using an alkyl halide and ammonia?

Propose a mechanism that accounts for the formation of the product.

Problem:Show how each of the following esters could be prepared using a carboxylic acid as one of the startingmaterials:

a. methyl butyrate (odor of apples) b. octyl acetate (odor of oranges)

Problem:Show how each of the following esters could be prepared using a carboxylic acid as one of the startingmaterials:

a. methyl butyrate (odor of apples) b. octyl acetate (odor of oranges)
See all solutions

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