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Chapter 18: Q62P (page 916)

Which of the following compounds reacts with HBr more rapidly?

Short Answer

Expert verified

Following Compound reacts with HBr more rapidly:

Step by step solution

01

Effects of substitutions on reactivity of benzene ring

Strongly activating substituents make the benzene ring reactive towards electrophilic substitution via electron donation by resonance.Mostly activating substituents are -NH2, -NHR, -NR2, -OH, -OR.

02

Reactivity of HBr towards second structure

The given compound is having one methoxy group (Strongly activating substituent) in para position. Electron donating group present in a benzene ring increases the reactivity because it forms stable carbocation intermediate by resonance electron donation.

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Most popular questions from this chapter

Question:a. How can aspirin be synthesized from benzene?b. Ibuprofen is the active ingredient in pain relievers such as Advil, Motrin and Nuprin. How can ibuprofen be synthesized from benzene?c. Acetaminophen is the active ingredient in Tylenol. How can acetaminophen be synthesized from benzene?

aspirin ibuprofen acetaminophen

Which amide bond is hydrolyzed in the first step of the conversion of temozolomide to methyldiazonium?

Question: Describe how naphthalene can be prepared from the given starting material.

Describe two ways to prepare anisole from benzene.

Show how each of the following compounds can be synthesized from benzene:

a. o-nitrophenol

b. p-nitroaniline

c. p-bromoanisole

d. anisole
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