Chapter 18: Q61P (page 915)
Describe two ways to prepare anisole from benzene.
Short Answer
1)

2)

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Chapter 18: Q61P (page 915)
Describe two ways to prepare anisole from benzene.
1)

2)

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Question: Propose a mechanism for each of the following reactions:
a.)

b.)

Explain why a secondary amine forms a nitrosamine rather than a diazonium ion when it reacts with a nitrosonium ion.

a. Explain why the following reaction leads to the products shown:

b. What product is obtained from the following reaction?

a. Rank the following compounds from greatest tendency to least tendency to undergo nucleophilic aromatic substitution:
chlorobenzene 1-chloro-2,4-dinitrobenzene p-chloronitrobenzene
b. Rank the same compounds from greatest tendency to least tendency to undergo electrophilic aromatic substitution.
In the mechanism for electrophilic aromatic substitution with a diazonium ion as the electrophile, why does nucleophilic attack occur on the terminal nitrogen of the diazonium ion rather than on the nitrogen that hasthe formal positive charge?
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