Chapter 14: Q77P (page 681)
Identify each of the following compounds from its molecular formula and its IR and 1H NMR spectra:
a. C6H120

b.C6H14O


c. C10H13NO3


d. C11H14O2



Short Answer
A.

b.

c.

d

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Chapter 14: Q77P (page 681)
Identify each of the following compounds from its molecular formula and its IR and 1H NMR spectra:
a. C6H120

b.C6H14O


c. C10H13NO3


d. C11H14O2



A.

b.

c.

d

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How can theirNMR spectra distinguish the following compounds?



a) For the following compounds which pairs of hydrogen (Ha and Hb) are enantiotopic hydrogens?
b) which pairs are diastereotopic hydrogens?

How an NMR distinguish between the compounds in each of the following pairs?
a.

b.

c.

d.

e.

f.

g.

h.

i.

j.

a. If two signals differ by 1.5 ppm in a 300 MHz spectrometer, by how much do they differ in a 500 MHz spectrometer?
b. If two signals differ by 90 Hz in a 300 MHz spectrometer, by how much do they differ in a 500 MHz spectrometer?
Draw a splitting diagram for Hbwere
a.Jba= 12 Hz andJbc= 6Hz b.Jba= 12 Hz andJbc= 12Hz

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