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Chapter 30: Question 30.32 (page 1225)

Draw the structure of the polymer that results from anionic polymerization of p-trichloromethylstyrene using ethylene oxide as the electrophile to terminate the chain.

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01

Polymers

Polymer is a chemical compound that contains many identical molecular repeating units. The polymer can be linear, branched, and three-dimensional long-chain molecules.

02

Reagents

Ethylene oxide is used as the 鈥渆lectrophile鈥� to terminate the chain.

03

Structure

Polystyrene is the polymer that results from the anionic polymerization of p-trichloromethylstyrene using ethylene oxide as the electrophile to terminate the chain.

Structure of polystyrene

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Most popular questions from this chapter

Draw the structure of the polymer formed by chain-growth polymerization of each monomer.

a.

b.

What monomer(s) are used to prepare each polymer or copolymer?

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b.

Although styrene undergoes both cationic and anionic polymerization equally well, one method is often preferred with substituted styrenes. Which method is preferred with each compound? Explain.

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b.

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The reaction of urea [NH2C=O]and formaldehyde role="math" localid="1648635328169" (CH2=O)forms a highly cross-linked polymer used in foams. Suggest a structure for this polymer. [Hint: Examine the structures of Bakelite (Figure 30.7) and Melmac (Problem 30.58).]

What polymers are formed from each monomer?

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