Chapter 14: Q4P (page 527)
Question: How many \(^{\bf{1}}{\bf{H}}\) NMR signals does each dimethylcyclopropane show?
a. 
b. 
c.
Short Answer
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Chapter 14: Q4P (page 527)
Question: How many \(^{\bf{1}}{\bf{H}}\) NMR signals does each dimethylcyclopropane show?
a. 
b. 
c.
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Label the protons in each highlighted CH2 group as enantiotopic, diastereotopic, or homotopic.
a.

b.

c.

How many NMR signals would you expect for each compound?
a.

b.

c.

Question: Label the signals due to Ha ,Hb and Hc in the 1 H NMR spectrum of acrylonitrile (CH2=CHCN ). Draw a splitting diagram for the absorption due to the proton Hc.

Question: For each compound, first label each different type of proton and then rank the protons in order of increasing chemical shift.
a.

b.

c.

Question:Answer the following questions about each of the hydroxy ketones: 1-hydroxybutan-2-one (A) and 4-hydroxybutan-2-one (B).

a. What is the molecular ion in the mass spectrum?
b. What IR absorptions are present in the functional group region?
c. How many lines are observed in the 13C NMR spectrum?
d. How many signals are observed in the 1H NMR spectrum?
e. Give the splitting observed for each type of proton as well as its approximate chemical shift.
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