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Chapter 22: Q34. (page 910)

Question: Draw the products of each reaction

a.

b.

Short Answer

Expert verified

Answer

a.

b.

Step by step solution

01

Step-by-Step Solution Step 1: Addition of Grignard and organolithium reagents to nitriles

Nitriles react with Grignard or organolithium reagent to give ketone via nucleophilic addition.

The mechanism of such a reaction is shown below:

Mechanism

02

Determination of product

Both the given reactions are examples of nitriles reacting with organometallic reagents. The products are given below:

a.

Product of reaction a.

b.

Product of reaction b.

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Most popular questions from this chapter

Devise a synthesis of each alcohol from organic alcohols having one or two carbons and any required reagents.

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Question: Oxytocin, sold under the trade name Pitocin, is a naturally occurring hormone used to stimulate uterine contractions and induce labor. Classify each amide in oxytocin as 1掳, 2掳, or 3掳.

Draw the products (including stereochemistry) of the following reactions.

What epoxide is needed to convertCH3CH2MgBrto each of the following alcohols, after quenching with water?

a.

b.

c.

d.

Question: Give the structure corresponding to each name.

  1. cyclohexyl propanoate
  2. cyclohexanecarboxamide
  3. 4-methylheptanenitrile
  4. vinyl acetate
  5. benzoic propanoic anhydride
  6. 3-methylhexanoyl chloride
  7. octyl butanoate
  8. N,N-dibenzylformamide
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