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Chapter 22: 34P (page 868)

Draw the product when each compound is treated with either (CH3)2CuLi , followed by H2O , HC鈮�CLi , followed by H2O .

a.

b.

c.

Short Answer

Expert verified

Answer

The addition products formed are shown below:

a.

b.

c.

Step by step solution

01

Step-by-Step Solution Step 1: Determination of 1,2- addition reaction

The 1,2-addition reaction takes place when you use an organolithium reagent in the case of 伪,尾 unsaturated carbonyl compounds.

It directly attacks the carbonyl carbon center, known as the 1,2-addition attack.

02

Determination of 1,4- addition reaction

The 1,4-addition reaction takes place when an organocuprate reagent is used in the case of 伪,尾 unsaturated carbonyl compounds. It attacks the alkene carbon of the fourth position from the carbonyl oxygen, known as the 1,4-addition attack.

03

The products formed in the given reactions

The addition products of compound a. are:

Reaction of compound b.

The addition products of compound b. are:

Reaction of compound b.

The addition products of compound c. are:

Reaction of compound c.

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Most popular questions from this chapter

Question: Without reading ahead in Chapter 22, state whether it should be possible to carry out each of the following nucleophilic substitution reactions.

a.

b.

c.

d.

Question:What reagents are needed to convert phenylacetonitrile (C6H5CH2CN) to each compound:

a.C6H5CH2CO(CH3)b.C6H5CH2COC(CH3)3c.C6H5CH2CHOd.C6H5CH2COOH

Question: Give the IUPAC or common name for each compound.

a.

b.

c.

d.

e.

f.

Draw the products (including stereochemistry) of the following reactions.

What alcohol is formed when each compound is treated with NaBH4in CH3OH?
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