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Chapter 22: 10P (page 868)

Draw a stepwise mechanism for the following reaction.

Short Answer

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Answer

The mechanism shown for the reduction of acid chloride by LiAlH4 to alcohol is shown below:

Step by step solution

01

Step-by-Step Solution Step 1: Function of  LiAlH4

LiAlH4 is one of the strongest reducing agents known to reduce carbonyl groups into alcohols.Besides reducing carbonyl groups into alcohols, LiAlH4 can also reduce acid chlorides into primary alcohols.

02

Mechanism of   in reducing acid chlorides into primary alcohols

The steps for reducing acid chlorides into primary alcohols with the help of LiAlH4 are shown below:

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Most popular questions from this chapter

Question: What carboxylic acid and alcohol are needed to prepare each ester by Fischer esterification?

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Draw the products formed when CH3COCH2CH2CH=CH2is treated with each reagent: (a)LiAlH4, then H2O ; (b) NaBH4in CH3OH ; (c) H2(1 equiv), Pd-C; (d)H2(excess), Pd-C; (e)NaBH4 (excess) inCH3OH ; (f) NaBD4in CH3OH

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