Chapter 28: Q3. (page 1106)
Question: Convert the ball-and-stick model to a Fischer projection.

Short Answer
Answer

Fischer projection of given compound
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Chapter 28: Q3. (page 1106)
Question: Convert the ball-and-stick model to a Fischer projection.

Answer

Fischer projection of given compound
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Question: Draw each stereogenic center using a Fischer projection formula.
The following isomerization reaction, drawn using D-glucose as starting material, occurs with all aldohexoses in the presence of base. Draw a stepwise mechanism that illustrates how each compound is formed.

A D-aldopentose A is reduced to an optically active alditol. Upon Kiliani-Fischer synthesis, A is converted to two D-aldohexoses, B and C. B is oxidized to an optically inactive aldaric acid. C is oxidized to an optically active aldaric acid. What are the structures of A-C?
Draw a Haworth projection for each compound using the structures in Figures 28.4 and 28.5.
Question: Referring to the structures in Figures 28.4 and 28.5, classify each pair of compounds as enantiomers, epimers, diastereomers but not epimers, or constitutional isomers of each other.
a. D-allose and L-allose
b.D-altrose and D-gulose
c.D-galactose and D-talose.
d.D-mannose and D-fructose.
e.D-fructose and D-sorbose
f.L-sorbose and L-tagatose
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