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Chapter 25: 53 (page 1043)

Draw the products formed when each amine is treated with [1] CH3I(excess); [2] Ag2O; [3] 鈭�. Indicate the major product when a mixture results.

a

b

c

d

Short Answer

Expert verified

a

b

c

d

Step by step solution

01

Reaction of amines 

Amines are involved in several reactions. For example, hydroamination involves the addition of the N-H bond of the amine on the double bond of the unsaturated compounds.

02

Formation of products 

a.

The reaction is shown below:

Formation of product in a.

b

The reaction is shown below:

Formation of product in b

c

The reaction is shown below:

Formation of product in c.

d

The reaction is shown below:

Formation of product in d.

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Most popular questions from this chapter

Devise a synthesis of each compound from the given starting material(s). Albuterol is a bronchodilator and proparacaine is a local anesthetic.

(a)

(b)

Explain the observed difference in the pKa values of the conjugate acids of amines A and B.

Tertiary ( 3掳) aromatic amines react with NaNO2 and HCl to afford products of electrophilic aromatic substitution. Draw a stepwise mechanism for this nitrosation reaction and explain why it occurs only on benzene rings with strong ortho, para activating groups.

Question: Draw a structure corresponding to each name.

a. 2,4-dimethylhexan-3-amine

b. N-methylpentan-1-amine

c. N-isopropyl-p-nitroaniline

d. N-methylpiperidine

e. N,N-dimethylethanaminef. 2-aminocyclohexanoneg. N-methylanilineh. m-ethylaniline

Question:The pKa of the conjugate acid of guanidine is 13.6, making it one of the strongest neutral organic bases. Offer an explanation.
See all solutions

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