a.The parent chain is of five carbons, so 鈥減ent鈥 is used as a prefix. Also, the chain is saturated. Therefore, 鈥渁ne鈥 will be used as a suffix. Fluorine and three methyl groups are present at the first, third, and fourth positions, respectively.
Numbering of carbon chain in (a)
Hence, the final IUPAC name of the compound is 1-fluoro-3,3,4-trimethylpentane.
b. In the given compound, the longest chain is of six carbon atoms, so 鈥渉ex鈥 will be used as a prefix. At first, second, and third positions, iodine, methyl, and ethyl group are present, respectively.
The compound is saturated, so 鈥渁ne鈥 will be used as a suffix.
Numbering of carbon chain in (b)
Hence, the final IUPAC name of the compound is 3-ethyl-1-iodo-2-methylhexane.
c. The parent chain carries six carbon atoms, so the prefix will be 鈥渉ex.鈥 The first and third carbon include a chlorine atom, and the fifth carbon contains two methyl groups. The suffix 鈥渁ne鈥 will be used as the compound is saturated.
Numbering of carbon chain in (c)
Hence, the final IUPAC name of the compound is 1,3-dichloro-5,5-dimethylhexane.
d. The given compound is a cyclic compound. The ring contains five carbon atoms. Hence, 鈥減ent鈥 will be used as a prefix. The compound is saturated. So, 鈥渁ne鈥 will be used as a suffix.
The numbering will be done according to alphabetical order. The numbering will be done from the bromine carbon atom. The iodine will get the third position.
Numbering of carbon chain in (d)
Hence, the final IUPAC name of the compound is 1-bromo-3-iodocyclopentane.
e. The parent chain is of eight carbon atoms. So, the prefix 鈥渙ct鈥 will be used. The suffix will 鈥渁ne鈥 is used as the compound is saturated. At the 6th position, a methyl group is used. The second carbon contains a chlorine atom.
Numbering of carbon chain in (e)
Hence, the final IUPAC name of the compound is 2-chloro-6,6-dimethyl-octane.
f. The parent chain is of 6 carbon atoms. Hence, 鈥渉ex鈥 will be used as a prefix. Due to saturated compound, the suffix will be 鈥渁ne鈥. At second carbon, iodine is present, and at fourth carbon, two methyl groups are present.
The compound is chiral with the configuration 鈥淩鈥 at the second position. The configuration should be mentioned while writing the IUPAC name.
Numbering of carbon chain in (f)
Hence, the final IUPAC name of the compound is (2R)-2-iodo-4,4-dimethylhexane.