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Chapter 7: PROBLEM 7.36 (page 286)

Question: Nicotine, a toxic and addictive component of tobacco, is synthesized from A using SAM. Write out the reaction that converts A into nicotine.

Short Answer

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ANSWER

Step by step solution

01

Substitution Reactions

The reactions in which a group/atom is substituted/replaced by another are referred to as substitution reactions.

02

SN2 (substitution nucleophilic bimolecular) Reactions

The substitution reactions in which the addition of a nucleophile and the elimination of the leaving group occur simultaneously are referred to as the substitution nucleophilic bimolecular (SN2) reaction.

03

Synthesis of nicotine

The reaction that converts A to nicotine is provided below.

Conversion of A to nicotine

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Most popular questions from this chapter

Give the IUPAC name for each compound

a)

b)

c)

d)

Question: Rank the species in each group in order of increasing nucleophilicity.

a.CH3CH2S- ,CH3CH2O-,CH3CO2- in CH3OH

b. CH3NH2 ,CH3SH,CH3OH in acetone

c. -OH ,F- ,Cl- in acetone

d. HS- ,F- ,I-in CH3OH

Question: Give the structure corresponding to each name.

a. 3-chloro-2-methylhexane

b. 4-ethyl-5-iodo-2,2-dimethyloctane

c. cis-1,3-dichlorocyclopentane

d. 1,1,3-tribromocyclohexane

e. sec-butyl bromide

f. 6-ethyl-3-iodo-3,5-dimethylnonane

Question: Rank the nucleophiles in each group in order of increasing nucleophilicity.

a. OH-,NH2- , H2O

b. OH- ,Br- , F-(polar aprotic solvent)

c. H2O, OH-,CH3CO2-

Question: CPC (cetylpyridinium chloride), an antiseptic found in throat lozenges and mouthwash, is synthesized by the following reaction. Draw the structure of CPC.
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