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Chapter 18: 23 P (page 706)

Devise a synthesis of each compound from the indicated starting material.

Short Answer

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Sulphonation reaction involves the substitution of the sulphonic group for the aromatic group. It occurs in the presence of sulfur trioxide and sulfuric acid.

Step by step solution

01

Sulphonation

Sulphonation reaction involves the substitution of the sulphonic group for the aromatic group. It occurs in the presence of sulfur trioxide and sulfuric acid.

02

Nitration

Thenitration reaction involves the substitution of the nitrate group on the aromatic group. It occurs in the presence of nitric acid and sulfuric acid.

03

Explanation

a. The given product has sulphonic and chloride groups. Therefore, sulphonation and chlorination processes are used to obtain the product.


b. The given product has acyl and nitro groups. Therefore, Friedel-Crafts acylation and nitration processes are used to obtain the product.


c. The given product has alkyl and bromine groups. Therefore, Friedel-Crafts alkylation and bromination processes are used to obtain the product.

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Most popular questions from this chapter

Draw the structure of A, an intermediate in the synthesis of the antipsychotic drug risperidone. Explain why three rings in risperidone are considered aromatic.

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Question: Draw a stepwise, detailed mechanism for the dienone鈥損henol rearrangement, a reaction that forms alkyl-substituted phenols from cyclohexadienones.

Draw the products formed when A and B are treated with each of the following reagents:

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