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Chapter 18: 23 P (page 706)

Devise a synthesis of each compound from the indicated starting material.

Short Answer

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Sulphonation reaction involves the substitution of the sulphonic group for the aromatic group. It occurs in the presence of sulfur trioxide and sulfuric acid.

Step by step solution

01

Sulphonation

Sulphonation reaction involves the substitution of the sulphonic group for the aromatic group. It occurs in the presence of sulfur trioxide and sulfuric acid.

02

Nitration

Thenitration reaction involves the substitution of the nitrate group on the aromatic group. It occurs in the presence of nitric acid and sulfuric acid.

03

Explanation

a. The given product has sulphonic and chloride groups. Therefore, sulphonation and chlorination processes are used to obtain the product.


b. The given product has acyl and nitro groups. Therefore, Friedel-Crafts acylation and nitration processes are used to obtain the product.


c. The given product has alkyl and bromine groups. Therefore, Friedel-Crafts alkylation and bromination processes are used to obtain the product.

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Most popular questions from this chapter

Question: Using resonance structures, explain why a nitroso group (-NO) is an ortho, para director that deactivates a benzene ring toward electrophilic attack.

Question: Reaction of p-cresol with two equivalents of 2-methylprop-1-ene affords BHT, a preservative with molecular formula C15H24O. BHT gives the following NMR spectral data: 1.4 (singlet, 18 H), 2.27 (singlet, 3 H), 5.0 (singlet, 1 H), and 7.0 (singlet, 2 H) ppm. What is the structure of BHT? Draw a stepwise mechanism illustrating how it is formed

Draw the products formed when A and B are treated with each of the following reagents:

(a)Br2,FeBr3; (b)HNO3,H2SO4l3; (c) CH3CH2COCl, AlCl3

Draw the products of each reaction.

What acid chloride would be needed to prepare each of the following ketones from benzene using a Friedel鈥揅rafts acylation?
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