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Consider the electron wave function

ψx=cxx≤1nmcxx≥1nm

where x is in nm.

a. Determine the normalization constant c.

b. Draw a graph of ψxover the interval role="math" localid="1650907186096" -5nm≤x≤5nm.

Provide numerical scales on both axes.

c. Draw a graph of ψx2over the interval role="math" localid="1650907657944" -5nm≤x≤5nm.

Provide numerical scales.

d. If 106 electrons are detected, how many will be in the interval

role="math" localid="1650908765290" -1.0nm≤x≤1.0nm?

Short Answer

Expert verified

a. The value of normalization constant is c=38

c. The number of electrons are detected in the given interval -1.0nm≤x≤1.0nmis 2.5×105.

Step by step solution

01

Part a Step 1: Given data

An electron wave function is given for the interval of x≤1nm,

ψx=cxand for the interval of x≥1nmis, ψx=cx.

02

Determination of the constant

Any wave function should satisfy the equation,known as the normalization condition which is the probability of finding a particle at position x.

Substituting the values of ψxin the given interval, we get,

∫-∞-1c2x2dx+∫-10c2x2dx+∫01c2x2dx+∫1∞c2x2dx=12∫1∞c2x2dx+2∫01c2x2dx=12c2-1x1∞+2c2x3301=123c2+2c2=183c2=1c=38

Therefore, the value of normalization constant isc=38

03

Part b Step 1: Graph of the wave function within -5 nm≤x≤5 nm

Plotting the values of wave function ψxalong y-axis and the position xalong x-axis we get the graph as:

04

Part c Step 1: Graph of the probability density within -5 nm≤x≤5 nm

Within the given limit, we can write the probability density, substituting the value of normalization constant as,

ψx2=38x2when x≤1nmand

ψx2=38x2when x≥1

Therefore, the ψx2versus xgraph should be as following:

05

Part d Step 1: Determination of the number of electron within -1.0 nm≤x≤1.0 nm

The probability of electron density within the given limit can be written as,

P-1nm≤x≤1nm=∫-11ψx2dxP-1nm≤x≤1nm=∫-11c2x2dxP-1nm≤x≤1nm=c2x33-11P-1nm≤x≤1nm=23c2P-1nm≤x≤1nm=23×38P-1nm≤x≤1nm=14

The number of electrons detected is106×14=2.5×105.

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