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An electron is confined in a harmonic potential well that has a spring constant of 2.0 N/m. a. What are the first three energy levels of the electron? b. What wavelength photon is emitted if the electron undergoes a 3 S 1 quantum jump?

Short Answer

Expert verified

a: 1: 7.809 * 10-20J

2: 2.342 * 10-19J

3: 3.904 * 10-19J

b: 636.38nm

Step by step solution

01

Given Parameters:

Spring constant (k) = 2.0N/m

Particle: electron

02

Part a:

Angular frequency of electron in this case is: km

=2.0N/m9.11×10-31kg=2.1953×1030=1.481×1015rad/sec

03

Energy levels

Now we know that energy level of quantum harmonic oscillator is E=(n-12)h2Ï€Ó¬

For, first energy level, n = 1

E1=h4πӬ=6.626×10-34JHz-14×3.14×1.481×1015rad/sec7.809×10-20J

For second energy level, n = 2

E2=3h4πӬ=3×6.626×10-34JHz-14×3.14×1.481×1015rad/sec2.342×10-19J

For third energy level, n = 3

E3=5h4πӬ=5×6.626×10-34JHz-14×3.14×1.481×1015rad/sec3.9045×10-19J

04

Part b:

If electron makes a jump from E3to E1.The energy of photon will be equal to the energy difference of these levels.

⇒hcλ=E3-E1

⇒λ=hcE3-E1SubstitutingValuesλ=6.626×10-34J/Hz×3×108m/s(3.9045×10-19)-(0.7809×10-19)J⇒λ=6.3638×10-7m⇒λ=636.38nm

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