/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Q13P How many milliliters of 0.202MNa... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

How many milliliters of 0.202MNaOHshould be added to 25.0 mlof 0.0233Msalicylic acid (2-hydroxybenzoic acid) to adjust the pHto 3.50?

Short Answer

Expert verified

The required volume ofNaOHis2.223mL

Step by step solution

01

Henderson-Hasselbalch equation

• The Henderson-Hasselbalch equation is a simplified formula that shows the connection between a solution's pH or pOH, pKa or pKb, and the ratio of concentrations of dissociated chemical species.

02

Determine the moles of salicylic acid

Calculate the moles of salicylic acid using the formula below: ηsalicylicacid=c×V

ηsalicylicacid=0.023M×25mL

ηsalicylicacid=0.5285mmo1

Consider the reaction:

localid="1663413505585" H2A+OH-⇌HA-+H2OH2A=0.5285-xHA-=x

03

Determine the required volume of NaOH

The Henderson-Hasselbach equation should be used next. pH=pKa+logHA-/H2A)3.50=2.972+logx0.5285-xx=0.4993mmol

Calculate the required volume of as follows V(NaOH)=n×cV(NaOH)=(0.4493mmol)×(0.202M)V(NaOH)=2.223mL

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Write the Ka2reaction of phosphoric acid (H3PO4)and the Kb2reaction of disodium oxalate(Na2C2O4).

The efficiency of a gas chromatography column is measured by a parameter called plate height (H, m m) , which is related to the gas flow rate (u, mL/min) by the van Deemter equation: H = A + B / u + Cu , where A , B , and C are constants. Prepare a spreadsheet with a graph showing values of as a function of u for u =4,6,8,10,20,20,40,50,60,70,80,90 and 10 mL/min. Use the values A = 1.65 m m , B = 25.8 m m .m L/min, and C = 0.023 6 m m.min/mL.

Protein and carbohydrates provide4.0Cal/g, whereas fat gives 9.0Cal/g. (Remember that 1 Calorie , with a capital C, is really 1kcal.) The weight percentages of these components in some foods are

Calculate the number of calories per gram and calories per ounce in each of these foods. (Use Table 1-4to convert grams into ounces, remembering that there are 16ounces in 1pound.)

Find the minimum detectable concentration if the average of the blanks is 1.05nAand 0.63nA.

The iodide (I-)content of a commercial mineral water was measured by two methods that produced wildly different results. Method A found0.23 milligrams of (I-)per litermg/Land method B found 0.009mg/L. When Mn2+ was added to the water, the I- content found by method A increased each time that moreMn2+was added, but results from method B were unchanged. Which of the Terms to Understand describes what is occurring in these measurements? Explain your answer. Which result is more reliable?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.