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Chapter 9: Q103P (page 391)

Draw the substitution and elimination products.

Short Answer

Expert verified

The following products are given below,

Step by step solution

01

Definition of elimination reaction

Elimination reaction is basically a reaction between alkyl bromide and a base in a step-by-step manner or in a concerted mechanism of bond breaking and making. During the elimination reaction, The C-X (X=halogen) and C-H bond should be in anti-periplanar fashion.

Example: E1, E2 E1cB mechanism.

02

Definition of substitution reaction

Substitution reaction is a nucleophilic reaction where the nucleophile attacks the compound either breaking the C-Br bond simultaneously with making the new bond or by forming carbocation 1st at the transition state by breaking of C-Br bond.

Example: SN1, SN2 mechanism.

03

Mechanism

The mechanism and products of the substitution and elimination reactions are given below,

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Most popular questions from this chapter

Rank the following species in each set from best nucleophile to poorest nucleophile.

What products are formed from the following reactions?

Which member in each pair in Problem 68 is a better leaving group?

Which reaction in each of the following pairs takes place more rapidly?

Draw the products of each of the following SN2/E2 reactions. If the products can exist as stereoisomers, show which stereoisomers are formed.

a.(3S,4S)-3-bromo-4-methylhexane + CH3O-

b.(3R,4R)-3-bromo-4-methylhexane + CH3O-

c.(3S,4R)-3-bromo-4-methylhexane + CH3O-

d.(3R,4S)-3-bromo-4-methylhexane + CH3O-
See all solutions

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