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Chapter 9: Q24P (page 419)

Which alkyl halide in each pair is more reactive in an E2 reaction with hydroxide ion?

Short Answer

Expert verified

1. It is a two step reaction.

2. In this carbocation is formed.

3. In this negative ion will attack from the side where there is less number of bulkier groups.

4. As the carbocation intermediate is formed so the stability order 3掳 carbocation>2掳 carbocation>1掳 carbocation

Step by step solution

01

How SN1 reaction proceed

1. It is a two step reaction.

2. In this carbocation is formed.

3. In this negative ion will attack from the side where there is less number of bulkier groups.

4. As the carbocation intermediate is formed so the stability order 3掳 carbocation>2掳 carbocation>1掳 carbocation

02

Final answer

a) In this secondary carbocation will form.

b) As bromine has greater size so it is better leaving group.

c) In this tertiary carbocation will form.

d) The other alkyl halide does not has B-hydrogens.

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Most popular questions from this chapter

What is the major elimination product obtained from an E2 reaction of each of the following alkyl halides with the hydroxide ion?

What is the product of the reaction of bromoethane with each of the following nucleophiles?

Two bromoethers are obtained from the reaction of the following alkyl dihalide with methanol. Draw the structures of the ethers.

a. Identify the substitution products that form when 2-bromo-2-methylpropane is dissolved in a mixture of 80% ethanol and 20% water.

b. Explain why the same products are obtained when 2-chloro-2-methylpropane is dissolved in a mixture of 80% ethanol and 20% water.

What is the major product formed when the following compounds undergo an E1 reaction?
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