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Chapter 1: Q-1-41P (page 2)

Which of the bonds in a carbon-oxygen double bond has more effective orbital overlap: the bond 蟽 or the bond 蟺 ?

Short Answer

Expert verified

The 蟽 bond in the carbon-oxygen double bond has a more effective orbital overlap.

Step by step solution

01

Definition of sigma and pi bond.

Sigma and pi bonds both are two categories of covalent bonds. Head-to-head overlap of atomic orbitals results in the formation of sigma bonds. While pi bonds are formed as a result of the lateral overlap of an atomic orbital.

02

Finding out the bond that has a more effective orbital overlap.

In the case of a carbon-oxygen double bond, 蟽 has more bond energy that makes it stronger and thus has a more effective overlap compared to 蟺 bond.

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Most popular questions from this chapter

A ketone can be prepared from the reaction of a nitrile with a Grignard reagent. Describe the intermediate formed in this reaction, and show how it can be converted to a ketone.

Predict the approximate bond angles for

  1. The C-N-C bond angle in(CH3)2 NH2+.
  2. The C-N-H bond angle in CH3CH2NH2.
  3. The H-C-N bond angle in(CH3)2NH.
  4. The H-C-O bond angle in CH3OCH3.

Draw the following orbitals:

a. 3sorbital

b. 4sorbitalc.

c. 3porbital

a.Which of the species have bond angles of 109.5掳?

b. Which of the species have bond angles of 120掳?

H2O H3O+ +CH3 BF3 NH3 +NH4 -CH3

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