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Chapter 1: Q-1-41P (page 2)

Which of the bonds in a carbon-oxygen double bond has more effective orbital overlap: the bond 蟽 or the bond 蟺 ?

Short Answer

Expert verified

The 蟽 bond in the carbon-oxygen double bond has a more effective orbital overlap.

Step by step solution

01

Definition of sigma and pi bond.

Sigma and pi bonds both are two categories of covalent bonds. Head-to-head overlap of atomic orbitals results in the formation of sigma bonds. While pi bonds are formed as a result of the lateral overlap of an atomic orbital.

02

Finding out the bond that has a more effective orbital overlap.

In the case of a carbon-oxygen double bond, 蟽 has more bond energy that makes it stronger and thus has a more effective overlap compared to 蟺 bond.

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Most popular questions from this chapter

Indicate the kind of molecular orbital (蟽 ,蟽 *,蟺 ,蟺 *) that results when the two atomic orbitals are combined:

The mass spectrum for a compound with molecular weight of 102 is shown below. Its IR spectrum has a broad, strong absorption at 3600 cm鈥�1 and a

medium absorption at 1360 cm鈥�1.

a.Identify the compound.

b.Show the mechanism for formation of the peak at m/z= 84.

Describe the orbital used in bonding and the bond angles in the following compounds:

a. CH3O-

b. CO2

c. H2CO

d. N2

e. BF3

Classify the following monosaccharides:

Rank the bonds from the most polar to least polar.

a. C - O,C - F,C - N

b. C - Cl > C - Br > C - I

c. H - O,H - N,H - C

d. C - H,C - C,C - N
See all solutions

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