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Name the following:

Short Answer

Expert verified

(a)Potassium butanoate

(b)Isobutyl butanoate

(c)N,N-dimethylhexanamide

(d) Pentanoyl chloride

(e) 5-methylhexanoic acid

(f) Propanamide

(g) 2-Azacyclopentanone

(h) Cyclopentanecarboxylic acid

(i) 5-Methyl-2-oxacyclohexanone

Step by step solution

01

Carboxylic acid derivatives

Carbonyl groups containing compounds other than an aldehyde or ketone are called carboxylic acid derivatives.

02

 Naming of salt of carboxylic acid

Here cation is named first then followed by name of acid and at the end ‘ate’ is used instead of ‘ic acid’.

In the given compound potassium is a cation and the acid has four carbon so will be butyl.

Potassium butanoate

The IUPAC name of compound is potassium butanoate.

The common name of the compound is potassium butyrate.

03

 Naming of ester

Esters have two alkyl groups: one is present attached to carbonyl group and other is attached to carboxyl oxygen. The group attached to carboxyl oxygen is written first then followed by parent chain naming and at last ‘ate’ is used instead of ‘ic acid’.

Here on carboxyl oxygen four carbon chain with iso-configuration is present so it is isobutyl group and the chain including carbonyl group is also having four carbon it is butyl group.

Isobutyl butanoate

The IUPAC name of compound is isobutyl butanoate.

Common name of compound is isobutyl butyrate.

04

 Step 4:  Naming of amide

In amide carbonyl group is present adjacent to instead of OH group. In amide instead of ‘oic acid’, ‘amide’ is used at the end.

Here two methyl groups are attached to amide nitrogen and six carbon chain is

present.

N,N-dimethylhexanamide

The IUPAC name of compound isN,N-dimethylhexanamide.

Common name of compound isN,N-dimethylhexanamide.

05

Naming of Acyl chlorides

In amide carbonyl group is attached to chlorine instead of OH group. In acyl chloride instead of ‘ic acid’, ‘yl chloride’ is used at the end. In case of cyclic acid carboxylic acid is replaced by carbonyl chloride.

Here chain has five carbon.

Pentanoyl chloride

The IUPAC name of compound isPentanoyl chloride.

Common name of compound is valeryl chloride.

06

 Step 6: Naming of carboxylic acid

In carboxylic acid carbonyl group is attached to OH group. Here the name of acid is written according to carbon present in chain and at the end ‘oic acid’ is used.

Chain has six carbon with methyl group substitution at carbon number five.In common name are used for numbering carbon adjacent to carbonyl group as is used for carbon adjacent to carbonyl group, for carbon adjacent to and so on.

Here methyl group is present four carbon away from carbonyl group so is used in naming

.

5-methylhexanoic acid

The IUPAC name of compound is5-methylhexanoic acid.

The common name of the compound is 8-methylcaproic acid.

07

 Naming of amide

Here carbonyl group is present adjacent to group instead of OH group so it is a amide. In amide instead of ‘oic acid’, ‘amide’ is used at the end.

Here three carbon are present in chain.

Propanamide

The IUPAC name of compound isPropanamide.

Common name of compound is Propionamide.

08

 Naming of ketone

Here carbonyl group is present adjacent to two alkyl group. In ketone ‘one’ is used at the end. The prefix aza- is used to give names to compounds where a carbon is replaced by a nitrogen atom.

Here ring is five membered.

2-Azacyclopentanone

The IUPAC name of compound is2-Azacyclopentanone.

Common name of compound is- gama butyrolactam.

09

Naming of cyclic carboxylic acid

In carboxylic acid carbonyl group is attached to OH group. Here the name of acid is written according to carbon present in chain and at the end ‘carboxylic acid’ is used.

Cyclopentanecarboxylic acid

The IUPAC name of compound iscyclopentanecarboxylic acid.

Common name of compound is cyclopentanecarboxylic acid.

10

Naming of ketone

Here carbonyl group is present next to two alkyl groups. In ketone ‘one’ is used at the end of the name. Oxa is used in compounds where a carbon atom is replaced by oxygen.

Here the ring is six-membered.

5-Methyl-2-oxacyclohexanone

The IUPAC name of compound is 5-Methyl-2-oxacyclohexanone.

Common name of compound is beta--Methyl and gama-valerolactone.

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Most popular questions from this chapter

Question: Is the acid-catalyzed hydrolysis of acetamide a reversible or an irreversible reaction? Explain.

When a compound with molecular formula C11H14O2undergoes acid-catalyzed hydrolysis, one of the products that is isolated gives the following H1NMR spectrum. Identify the compound.

Catalytic antibodies catalyze a reaction by forcing the conformation of the substrate in the direction of the transition state. The synthesis of antibody is carried out in the presence of a transition state analog-a stable molecule that structurally resembles the transition state. This causes an antibody to be generated that recognizes and binds to the transition state, thereby stabilizing it. For example, the following transition state analog has been used to generate a catalytic antibody that catalyzes the hydrolysis of structurally similar ester:

a. Draw a possible transition state for the hydrolysis of the reaction.

b. The following transition state analog is used to generate a catalytic antibody for the catalysis of ester hydrolysis. Draw the structure of an ester whose rate of hydrolysis would be increased by this catalytic antibody.

c. Design a transition state analog that catalyzes amide hydrolysis at the amide group indicated.

When butanoic acid and 18O-labelled methanol react under acidic conditions, what compounds are labelled when the reaction has reached equilibrium?

What alkyl bromide would you use in a Gabriel synthesis to prepare each of the following amines?

  1. Pentylamine

  2. Iso hexyl amine

  3. Benzylamine

  4. Cyclohexylamine

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