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Chapter 4: Q94P (page 185)

For each of the following structures, draw the most stable chair conformer.

Short Answer

Expert verified

We have to draw the most stable chair conformer:

a)

b)

Step by step solution

01

What is axial position and equatorial position

Axial position= In cycloheaxane a bond which is parallel to the axis of the ring is called its axial position.

Equatorial position= In cycloheaxane a bond which is perpendicular to the axis of the ring is called its equatorial position.

02

How to give priority 

The groups with the highest priority will placed on the equatorial positions and rest of the substituents will placed on the axial positions.

  1. Assign the priority order to the groups on the basis of atomic number. Higher the atomic number get highest priority.
  2. Double bond is considered as carbon is attached to 2 carbons.
  3. Triple bond is considered as carbon is attached to 3 carbons.

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Most popular questions from this chapter

Draw skeletal structures for the compounds in Problem 3, including any cis-trans isomers.

Assign relative priorities to each set of substituents:

a. -CH2CH2CH3 -CH(CH3)2 -CH=CH2 -CH3

b. -CH2NH2 -NH2 -OH -CH2OH

c. -C(=O)CH3 -CH=CH2 -Cl -C鈮

Tamoxifen slows the growth of some breast tumors by binding to estrogen receptors. Is tamoxifen an Eor a Zisomer?

A student decided that the configuration of the asymmetric centers in a sugar such as d-glucose could be determined rapidly by simply assigning the Rconfiguration to an asymmetric center with an OH group on the right and the Sconfiguration to an asymmetric center with an OH group on the left. Is

he correct? (We will see in Chapter 20 that the 鈥渄鈥� in d-glucose means that the OH group on the bottommost asymmetric center is on the right.)

Stereoisomers with two asymmetric centres are called ___ if the configuration of both asymmetric centers in one stereoisomer is the opposite of the configuration of the asymmetric centers in the other stereoisomer.

b. Stereoisomers with two asymmetric centers are called ___ if the configuration of both asymmetric centers in one stereoisomer is the same as the configuration of the asymmetric centers in the other stereoisomer.

c. Stereoisomers with two asymmetric centers are called ___ if one of the asymmetric centers has the same configuration in both stereoisomers and the other asymmetric center has the opposite configuration in the two stereoisomers.
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