/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Q-93P Question: Draw structures for ea... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

Question: Draw structures for each of the following:

a.(S)-1-bromo-1-chlorobutane

b.(2R,3R)-2,3-dichloropentane

c.an achiral isomer of 1,2-dimethylcyclohexane

d.a chiral isomer of 1,2-dibromocyclobutane

e. two achiral isomers of 3,4,5-trimethylheptane

Short Answer

Expert verified

We have to draw the structures of the following compounds:

Step by step solution

01

Step 1: How to find configuration

1. Assign the priority order to the groups on the basis of atomic number. Higher the atomic number get highest priority.

2. Double bond is considered as carbon is attached to 2 carbons.

3. Triple bond is considered as carbon is attached to 3 carbons.

4. Lowest priority group is always on dotted line.

5. If lowest priority group is not on dotted line then exchange the group with that group which is on dotted line and to maintain the stability of the com[pound we have to exchange other two compounds also.

6. Then according to priority order we have to determine the configuration. We have to go highest priority order to lowest priority order and if we go clockwise then it is R configuration and if we go anticlockwise then it is S configuration.

02

How to naming compounds

1. Select longest parent chain.

2. Functional group has to be given lowest number.

3. If two Functional groups are present then give number according to priority order.

03

What is asymmetric centre or chiral carbon

Chiral objects are those objects which have no same mirror images. The mirror images don’t superimpose each other. whose mirror images superimpose each other that compounds are called achiral objects.

Chiral carbon is that carbon atom which is bonded to four different groups.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

a) Do the following compounds have any asymmetric centers?

b) Are the compounds chiral? (Hint: Make models.)

  1. CH2=C=CH2
  2. CH3CH=C=CHCH3

Citrate synthase, one of the enzymes in the series of enzyme-catalyzed reactions known as the citric acid cycle (Section 24.9), catalyzes the synthesis of citric acid from oxaloacetic acid and acetyl-CoA. If the synthesis is carried out with acetyl-CoA that contains radioactive carbon (14C) in the indicated position (Section 1.1), the isomer shown here is obtained.

a. Which stereoisomer of citric acid is synthesized: Ror S?

b. If the acetyl-CoA used in the synthesis contains 12C instead of 14C, will the product of the reaction be chiral or achiral?

What is the configuration of each of the asymmetric centers in the following compounds?

Stereoisomers with two asymmetric centres are called ___ if the configuration of both asymmetric centers in one stereoisomer is the opposite of the configuration of the asymmetric centers in the other stereoisomer.

b. Stereoisomers with two asymmetric centers are called ___ if the configuration of both asymmetric centers in one stereoisomer is the same as the configuration of the asymmetric centers in the other stereoisomer.

c. Stereoisomers with two asymmetric centers are called ___ if one of the asymmetric centers has the same configuration in both stereoisomers and the other asymmetric center has the opposite configuration in the two stereoisomers.

Of all possible cyclooctane that have one chloro substituent and one methyl substituent which one do not have any asymmetric center?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.