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Chapter 8: Q32 P (page 350)

What are the products of the following reactions, assuming that one equivalent of each reagent is used in each reaction? Disregard stereoisomers.

Short Answer

Expert verified

a.

b.

Step by step solution

01

How reaction proceed

a) The chlorine adds so that the positive charge in the resonance contributor is on a secondary allylic carbon and if the chlorine had added to the other double bond the positive charge would be on a primary allylic carbon.

b)The proton adds so that the positive charge in the carbocation by a tertiary allylic and a secondary allylic carbon and if the proton had added to the other double bond the positive charge would be shared by two secondary allylic carbons.

02

Final answer

a)

b)

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