Chapter 14: Q30P (page 746)
Give common names for the following compounds

Short Answer
Answer
(a

(e



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Chapter 14: Q30P (page 746)
Give common names for the following compounds

Answer
(a

(e



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(a) When ethylene oxide is treated with anhydrous HBr gas, the major product is 1,2-dibromoethane. When ethylene oxide is treated with concentrated aqueous HBr, the major product is ethylene glycol. Use mechanisms to explain these results.
(b) Under base-catalyzed conditions, several molecules of propylene oxide can react to give short polymers. Propose a mechanism for the base-catalyzed formation of the following trimer.

Question. Propose a mechanism for the following reaction.
Give the expected products of the following reactions. Include a protonation step where necessary.
Which of the following ethers can be formed in good yield by condensation of the corresponding alcohols? For those that cannot be formed by condensation, suggest an alternative method that will work.
(a)
(b)
(c)
Question: (a) Predict the values of m/zand the structures of the most abundant fragments you would observe in the mass spectrum of di-n-propyl-ether.
(b) Give logical fragmentations to account for the following ions observed in the mass spectrum of 2-methoxypentane: 102,87,71,59,31.
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