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Chapter 18: 5P (page 684)

What product is formed when benzene is treated with each organic halide in the presence of AlCl3.

Short Answer

Expert verified

The reaction that involves the replacement of an aromatic proton (hydrogen atom on the benzene ring) by an alkyl group is named as Friedel-Crafts alkylation reaction.

The reaction proceeds by the generation of an alkyl cation from an alkyl halide.

Step by step solution

01

Friedel-Crafts alkylation reaction

The reaction that involves the replacement of an aromatic proton (hydrogen atom on the benzene ring) by an alkyl group is named as Friedel-Crafts alkylation reaction.

The reaction proceeds by the generation of an alkyl cation from an alkyl halide.

02

Friedel-Crafts acylation reaction

The reaction that involves the replacement of an aromatic proton by an acyl (R-C=O) group is named as Friedel-Crafts acylation reaction.

03

Friedel-Crafts reactions

The reaction of benzene with the given organic halides are as follows:

a

b

c

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Most popular questions from this chapter

Synthesize each compound from benzene

Draw the products formed when phenol ( C6H5OH) is treated with each set of reagents.

a. [1] HNO3, H2SO4; [2] Sn, HCl

b. [1] CH3CH22COCl,AlCl3; [2] Zn(Hg), HCl

c. [1] CH3CH2Cl,AlCl3; [2]Br2,h谓

d. [1] CH32CHCl,AlCl3; [2] KMnO4

In Step [2] of Mechanism 18.1, loss of a proton to form the substitution product was drawn using one resonance structure only. Use curved arrows to show how the other two resonance structures can be converted to the substitution product (PhE) by removal of a proton with: B.

Question: Draw a stepwise mechanism for the following substitution. Explain why 2-chloropyridine reacts faster than chlorobenzene in this type of reaction.

Draw a stepwise mechanism for the following reaction.
See all solutions

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