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Chapter 8: Q44E (page 451)
Which of the period 2 homonuclear diatomic molecules are predicted to be paramagnetic?
The period 2 homonuclear diatomic molecules are predicted to be paramagnetic are B2 and O2.
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Calculate the bond order for an ion with this configuration: \({\left( {{{\bf{\sigma }}_{{\bf{2s}}}}} \right)^{\bf{2}}}{\left( {{\bf{\sigma }}_{{\bf{2s}}}^{\bf{*}}} \right)^{\bf{2}}}{\left( {{{\bf{\sigma }}_{{\bf{2px}}}}} \right)^{\bf{2}}}{\left( {{{\bf{\pi }}_{{\bf{2py}}}}{\bf{,}}{{\bf{\pi }}_{{\bf{2pz}}}}} \right)^{\bf{4}}}{\left( {{\bf{\pi }}_{{\bf{2py}}}^{\bf{*}}{\bf{,\pi }}_{{\bf{2pz}}}^{\bf{*}}} \right)^{\bf{3}}}\).
Sulfuric acid is manufactured by a series of reactions represented by the following equations:
\(\begin{array}{l}{{\rm{S}}_{\rm{8}}}{\rm{(s) + 8}}{{\rm{O}}_{\rm{2}}}{\rm{(g)}} \to {\rm{8S}}{{\rm{O}}_{\rm{2}}}{\rm{(g)}}\\{\rm{2S}}{{\rm{O}}_{\rm{2}}}{\rm{(g) + }}{{\rm{O}}_{\rm{2}}}{\rm{(g)}} \to {\rm{2S}}{{\rm{O}}_{\rm{3}}}{\rm{(g)}}\\{\rm{S}}{{\rm{O}}_{\rm{3}}}{\rm{(g) + }}{{\rm{H}}_{\rm{2}}}{\rm{O(l)}} \to {{\rm{H}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}{\rm{(l)}}\end{array}\)
Draw a Lewis structure, predict the molecular geometry by VSEPR, and determine the hybridization of sulfur for the following:
(a) circular \({{\rm{S}}_{\rm{8}}}\)molecule
(b) \({\rm{S}}{{\rm{O}}_{\rm{2}}}\)molecule
(c) \({\rm{S}}{{\rm{O}}_{\rm{3}}}\)molecule
(d) \({{\rm{H}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}\)molecule (the hydrogen atoms are bonded to oxygen atoms)
What is the hybridization of the selenium atom in SeF4?
If molecular orbitals are created by combining five atomic orbitals from atom A and five atomic orbitals from atom B combine, how many molecular orbitals will result?
Acetic acid, H3CC(O)OH, is the molecule that gives vinegar its odor and sour taste. What is the hybridization of the two carbon atoms in acetic acid?
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