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Your laboratory assignment for the week is to measure the specific heat ratio γof carbon dioxide. The gas is contained in a cylinder with a movable piston and a thermometer. When the piston is withdrawn as far as possible, the cylinder's length is 20cm. You decide to push the piston in very rapidly by various amounts and, for each push, to measure the temperature of the carbon dioxide. Before each push, you withdraw the piston all the way and wait several minutes for the gas to come to the room temperature of 211°C. Your data are as follows:

Use the best-fit line of an appropriate graph to determine γfor carbon dioxide.

Short Answer

Expert verified

The best-fit line of an appropriate graph to determine γfor carbon dioxide is1.292

Step by step solution

01

Given Information

Cylinder length=20cm

Temperature=211∘C

Given Data:

02

Explanation

Since the process is adiabatic, we know that pVγ=const. Therefore we can write

p1V1γ=p2V2γ

This allows us to express the ratio of pressures as

p2p1=V1V2γ

Rearranging the ideal gas law for the case when the number of moles is constant, we get

p1V1T1=p2V2T2⇒p2p1=V1V2T2T1

Having already expressed the ratio of pressures, we can write

V1V2γ=V1V2T2T1

Dividing both sides by the ratio of volumes and by the power rules, we can write

V1V2γ-1=T2T1

03

Explanation

Having done this derivation, what we can do is find out the ratios for all the compression trials. Also, we must take note that the ratio of the volume will be equal to the ratio of the initial (total) length of the cylinder by the length it reaches. That is, our list of volumes, in units of V1, will be

1.333,2.000,2.857,4.000.

By a similar manner, we can construct a list of temperatures in the experiments, giving the temperatures after the compression in units of T1. Considering that we must convert to Kelvin, we would have

1.0476,1.1598,1.3027,1.4388

Now we can plot the temperature ratios as a function of the volume ratios. After scattering, we can fit a power function and from that determine the γ-1parameter. A such graph is given below:

04

Final Answer

Therefore, as we can see from the fitting parameters, we have

γ-1=0.2918

γ=1.292

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