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Calculate (a) the radial wave function and (b) the radial probability density at r=12aBfor an electron in the 1s state of hydrogen. Give your answers in terms ofaB

Short Answer

Expert verified

(a) The radial wave function for an electron at r=12aBin the 1sstate of hydrogen isR1sr=0.34aB-3/2.

(b) The radial probability density atr=12aBin the1sstate of hydrogen isPrr=0.37aB-1.

Step by step solution

01

Part (a) Step 1 : Given Information

We have find the radial wave function for an electron in the 1sstate of hydrogen at r=12aB

02

Part (a) Step 2 : Simplification

The radial wave function of hydrogen in the 1sstate is

R1sr=1Ï€aB3e-r/aB(aBis Bohr radius and ris distance of electron from nuclei)

localid="1650366257896" ⇒R1s12aB=1πaB3e-1/2=0.34aB-3/2

03

Part (b) Step 1 : Given Information

We have find the probability density for an electron in the 1sstate of hydrogen at r=12aB

04

Part (b) Step 2 : Simplification

The probability density is

Prr=4Ï€r2Rnlr2 (aBis Bohr radius and ris distance the distance of electron from nuclei)

localid="1650366757646" ⇒Pr12aB=4πaB221πaB3e-1/22=0.37aB-1

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