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Suppose that a collection of quantum harmonic oscillators occupies the lowest four energy levels, and the spacing between levels is 0.4eV. What is the complete emission spectrum for this system? That is, what photon energies will appear in the emissions? Include all energies, whether or not they fall in the visible region of the electromagnetic spectrum.

Short Answer

Expert verified

The photon energies for the given system are0.4eV (three transitions), 0.4eV(Two transitions), and1.2eV (one transition).

Step by step solution

01

Concept Introduction

The expression for the energy of the oscillator is given by,

EN=狈丑蝇0+E0

Here N=0,1,2,....

The angular frequency is given by,

0=ksm

Here0 is the angular frequency,ks is the spring constant,m is the mass.

The ground state energy of the harmonic oscillator is given by,

E0=12h蝇0

02

Given data

The spacing between the energy level is given by,

螖贰=0.4eV

h蝇0=0.4eV

03

Calculate the photon energy that will appear in the emissions.

The expression for energy of the photon which is emitted during the transition from 32is given by,

E3E2=(3h蝇0+E0)(2h蝇0+E0)=h蝇0

Substitute0.4eV for h蝇0into the above equation,

E3E2=0.4eV

The expression for energy of the photon which is emitted during the transition from30is given by,

E3E0=(3h蝇0+E0)(E0)=3h蝇0

Substitute0.4eV for h蝇0into the above equation,

E3E0=3(0.4eV)=1.2eV

The expression for energy of the photon which is emitted during the transition from20is given by,

E2E0=(2h蝇0+E0)(E0)=2h蝇0

Substitute0.4eVfor h蝇0into the above equation,

E3E0=2(0.4eV)=0.8eV

The expression for energy of the photon which is emitted during the transition from31is given by,

E3E1=(3h蝇0+E0)(h蝇0+E0)=2h蝇0

Substitute 0.4eV for h蝇0into the above equation,

E3E0=2(0.4eV)=0.8eV

The expression for energy of the photon which is emitted during the transition from10is given by,

E1E0=(h蝇0+E0)(E0)=h蝇0

Substitute0.4eV for h蝇0into the above equation,

E3E0=0.4eV

Therefore, the photon energies for the given system are 0.4eV(three transitions),0.4eV (Two transitions), and 1.2eV(one transition).

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Most popular questions from this chapter

The photon energy for green light lies between the values for red and violet light. What is the approximate energy of the photons in green light? The intensity of sunlight above the Earth鈥檚 atmosphere is about 1400 W (J/s) per square meter. That is, when sunlight hits perpendicular to a square meter of area, about 1400 W of energy can be absorbed. Using the photon energy of green light, about how many photons per second strike an area of one square meter? (This is why the lumpiness of light was not noticed for so long.)


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