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In Problem 7.28you found the density of states and the chemical potential for a two-dimensional Fermi gas. Calculate the heat capacity of this gas in the limit role="math" localid="1650099524353" kT≪εF· Also show that the heat capacity has the expected behavior when kT≫εF. Sketch the heat capacity as a function of temperature.

Short Answer

Expert verified

The heat capacity of the gas in the limit is CV=N(kπ)2T3εF.

The graph of heat capacity as a function of temperature is

Step by step solution

01

Given information

We have been given that the density of states and the chemical potential for a two-dimensional Fermi gas which we have found earlier in Problem 7.28isg(ε)=NεF.

We need to find the heat capacity of this gas in the limit kT≪εFand show that the heat capacity has the expected behavior when kT≫εF. Also we need to sketch the heat capacity as a function of temperature.

02

Simplify

The total energy is given by the following integral:

U=∫0∞εg(ε)n¯FD(ε)dε (Let this equation be (localid="1650103209259" 1))

We have found the energy density earlier in Problem 7.28such as

localid="1650102270353" g(ε)=NεF

Substitute the value of g(ε)in equation (localid="1650103517684" 1), we get:

U=NεF∫0∞εn¯FD(ε)dε

Integrating by parts, we get:

U=NεFε22n¯FD|0∞-NεF∫0∞ε22∂n¯FD∂εdε (Let this equation be (2))

If we substitute ε=0, the integral will become zero due to the dependence of the term on ε2and the first term vanishes.

The equation (2) reduces to :

U=-NεF∫0∞ε22∂n¯FD∂εdε (Let this equation be (3))

We know that n¯FD=1e(e-μ)kT+1

Taking derivative with respect to ε, we get:

localid="1650103912932" ∂n¯FD∂ε=∂1e(ε-μ)kT+1∂ε

∂n¯FD∂ε=-1kTe(ε-μ)kT(e(ε-μ)kT+1)2

Let (ε-μ)kT=x, then we can write as:

dx=dεkT

We also need to change the boundaries of integration, so:

ε→∞ x→∞

ε→0 x→-μkT

As kT≪μ, we can put -∞as the lower limit of integration.

The integral in equation (3) will become:

U=N2εF∫-∞∞ε2ex(ex+1)2dx (Let this equation be (localid="1650114310341" 4))

03

finding the values of integrals

Now expanding ε2about μusing Taylor series, we get:

ε2=μ2+2μ(ε-μ)x+(ε-μ)x2ε2=μ2+2μ(kTx)+(kTx)2

By substituting the value of in equation (4), we get three integrals say I1,I2,I3

The equation (4) will become:

U=N2εF[I1+I2+I3] (Let this equation be (5))

where,

I1=μ2∫-∞∞ex(ex+1)2dxI2=2kTμ∫-∞∞xex(ex+1)2dxI3=(kT)2∫-∞∞x2ex(ex+1)2dx

Simplifying the integrals I1,I2,I3, we get:

I1=μ2

The second integral is odd integral and the limits of integration are from to , so this integral is simply zero.

I2=0

I3=(kT)2Ï€23=(kTÏ€)23

Substitute the values of in equation (5), we get:

U=N2εFμ2+(kTπ)23

Let μ=εF, we get:

U=N2εFεF2+(kTπ)23U=NεF2+N(kTπ)26εF

The heat capacity is the partial derivative of with respect to the temperature, that is:

CV=∂U∂TCV=∂NεF2+N(kTπ)26εF∂TCV=N(kπ)2T3εF

04

Graph

The graph of the heat capacity as a function of temperature is linear, where the slope of the line is Slope=N(kπ)23εF.

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Most popular questions from this chapter

Change variables in equation 7.83 to λ=hc/ϵ and thus derive a formula for the photon spectrum as a function of wavelength. Plot this spectrum, and find a numerical formula for the wavelength where the spectrum peaks, in terms of hc/kT. Explain why the peak does not occur at hc/(2.82kT).

Calculate the condensate temperature for liquid helium-4, pretending that liquid is a gas of noninteracting atoms. Compare to the observed temperature of the superfluid transition, 2.17K. ( the density of liquid helium-4 is 0.145g/cm3)

Sometimes it is useful to know the free energy of a photon gas.

(a) Calculate the (Helmholtz) free energy directly from the definition

(Express the answer in terms of T' and V.)

(b) Check the formula S=-(∂F/∂T)Vfor this system.

(c) Differentiate F with respect to V to obtain the pressure of a photon gas. Check that your result agrees with that of the previous problem.

(d) A more interesting way to calculate F is to apply the formula F=-kTlnZ separately to each mode (that is, each effective oscillator), then sum over all modes. Carry out this calculation, to obtain

F=8πV(kT)4(hc)3∫0∞x2ln1-e-xdx

Integrate by parts, and check that your answer agrees with part (a).

At the surface of the sun, the temperature is approximately 5800 K.

(a) How much energy is contained in the electromagnetic radiation filling a cubic meter of space at the sun's surface?

(b) Sketch the spectrum of this radiation as a function of photon energy. Mark the region of the spectrum that corresponds to visible wavelengths, between 400 nm and 700 nm.

(c) What fraction of the energy is in the visible portion of the spectrum? (Hint: Do the integral numerically.)

In a real hemoglobin molecule, the tendency of oxygen to bind to a heme site increases as the other three heme sites become occupied. To model this effect in a simple way, imagine that a hemoglobin molecule has just two sites, either or both of which can be occupied. This system has four possible states (with only oxygen present). Take the energy of the unoccupied state to be zero, the energies of the two singly occupied states to be -0.55eV, and the energy of the doubly occupied state to be -1.3eV(so the change in energy upon binding the second oxygen is -0.75eV). As in the previous problem, calculate and plot the fraction of occupied sites as a function of the effective partial pressure of oxygen. Compare to the graph from the previous problem (for independent sites). Can you think of why this behavior is preferable for the function of hemoglobin?

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