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What mass of sample in Figure 28-3 is expected to give a sampling standard deviation of \( \pm 6\% \)?

Short Answer

Expert verified

The mass of the sample which produces the relative standard deviation of \(1\% \)

Step by step solution

01

Definition of Standard deviation.

  • The standard deviation is a measure of how far something deviates from the mean (for example, spread, dispersion, or spread). A "typical" variation from the mean is represented by the standard deviation.
  • Because it returns to the data set's original units of measurement, it's a common measure of variability.
  • The standard deviation, defined as the square root of the variance, is a statistic that represents the dispersion of a dataset relative to its mean.
02

Determine the Sampling Standard deviation.

In this task we will calculate the mass of sample in Figure \(28 - 3\) expected to give a sampling standard deviation of\( \pm 6\% \).

Here we will use the equation \(28 - 5\) for relative variance\(\left( {{R^2}} \right)\) :

\(\begin{array}{l}{R^2} = {\left( {\frac{{{\delta _n}}}{n}} \right)^2}\\ = \frac{{pq}}{n}n\\{R^2} = pq\end{array}\)

Where, \(p\) and \(q\) are the fraction of particles present

Next we will rearrange the equation \(28 - 5\)to the following and calculate the mass of sample:

\(\begin{array}{l}m{R^2} = {K_a}\\m = \frac{{{K_a}}}{{{R^2}}}\\m = \frac{{36\;{\rm{g}}}}{{{6^2}}}\\m = 1\;{\rm{g}}\end{array}\)

Where, \(R\) is the relative standard deviation and \({K_a}\) is the sampling constant

Therefore, the mass of the sample which produces the relative standard deviation of \(1\% \)

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Most popular questions from this chapter

To pre-concentrate cocaine and benzoylecgonine from river water described at the opening of this chapter, solid-phase extraction was carried out at \({\rm{pH}}\,\,2\) using the mixed-mode cation-exchange resin in Figure 28-19. After passing \(500\;{\rm{mL}}\)of river water through \(60{\rm{mg}}\)of resin, the retained analytes were eluted first with \(2\;{\rm{mL}}\)of \({\rm{C}}{{\rm{H}}_3}{\rm{OH}}\)and then with \(2\;\,\,{\rm{mL }}of\,\,\,2\% \) ammonia solution in\({\rm{C}}{{\rm{H}}_3}{\rm{OH}}\). Explain the purpose of using \({\rm{pH}}2\) for retention and dilute ammonia for elution.

In analyzing a lot with random sample variation, you find a sampling standard deviation of \({\bf{65}}\% .\)Assuming negligible error in the analytical procedure, how many samples must be analyzed to give \(9{\bf{5}}\% \)confidence that the error in the mean is within\(64\% \)of the true value? Answer the same question for a confidence level of \(90\% \).

In an experiment analogous to that in Figure 28-3, the sampling constant is found to be \({K_{\rm{s}}} = 20\;{\rm{g}}.\)

(a) What mass of sample is required for a \( \pm 2\% \)sampling standard deviation?

(b) How many samples of the size in part (a) are required to produce \(90\% \)confidence that the mean is known to within\(1.5\% \)?

How does solid-supported liquid-liquid extraction differ from solid-phase extraction?

Why is it advantageous to use large particles \(\left( {{\bf{50}}{\rm{ }}\mu {\bf{m}}} \right)\) for solid phase extraction, but small particles \(\left( {{\bf{5}}{\rm{ }}\mu {\bf{m}}} \right)\) for chromatography?

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