Chapter 28: Q4P (page 790)
What mass of sample in Figure 28-3 is expected to give a sampling standard deviation of \( \pm 6\% \)?
Short Answer
The mass of the sample which produces the relative standard deviation of \(1\% \)
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Chapter 28: Q4P (page 790)
What mass of sample in Figure 28-3 is expected to give a sampling standard deviation of \( \pm 6\% \)?
The mass of the sample which produces the relative standard deviation of \(1\% \)
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To pre-concentrate cocaine and benzoylecgonine from river water described at the opening of this chapter, solid-phase extraction was carried out at \({\rm{pH}}\,\,2\) using the mixed-mode cation-exchange resin in Figure 28-19. After passing \(500\;{\rm{mL}}\)of river water through \(60{\rm{mg}}\)of resin, the retained analytes were eluted first with \(2\;{\rm{mL}}\)of \({\rm{C}}{{\rm{H}}_3}{\rm{OH}}\)and then with \(2\;\,\,{\rm{mL }}of\,\,\,2\% \) ammonia solution in\({\rm{C}}{{\rm{H}}_3}{\rm{OH}}\). Explain the purpose of using \({\rm{pH}}2\) for retention and dilute ammonia for elution.
In analyzing a lot with random sample variation, you find a sampling standard deviation of \({\bf{65}}\% .\)Assuming negligible error in the analytical procedure, how many samples must be analyzed to give \(9{\bf{5}}\% \)confidence that the error in the mean is within\(64\% \)of the true value? Answer the same question for a confidence level of \(90\% \).
In an experiment analogous to that in Figure 28-3, the sampling constant is found to be \({K_{\rm{s}}} = 20\;{\rm{g}}.\)
(a) What mass of sample is required for a \( \pm 2\% \)sampling standard deviation?
(b) How many samples of the size in part (a) are required to produce \(90\% \)confidence that the mean is known to within\(1.5\% \)?
How does solid-supported liquid-liquid extraction differ from solid-phase extraction?
Why is it advantageous to use large particles \(\left( {{\bf{50}}{\rm{ }}\mu {\bf{m}}} \right)\) for solid phase extraction, but small particles \(\left( {{\bf{5}}{\rm{ }}\mu {\bf{m}}} \right)\) for chromatography?
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