Chapter 16: Q23P (page 392)
State two ways to make standard triiodide solution.
Short Answer
To make standard triiodide solution is to mix together and then add a strong acid such as .
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Chapter 16: Q23P (page 392)
State two ways to make standard triiodide solution.
To make standard triiodide solution is to mix together and then add a strong acid such as .
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Some people have an allergic reaction to the food preservative sulfite , which can be measured by instrumental methods 37 or by a redox titration: To 50.0mL of wine were added 50.0mL of solution containing . Acidification with 1.0 mL of quantitatively converted role="math" localid="1663606948648" into . The reacted with to generate role="math" localid="1663607055826" , leaving excess in solution. The excess required of to reach a starch end point.
(a) Write the reaction that occurs when is added to KI and explain why 6.0 gKI were added to the stock solution. Is it necessary to measure out 6.0 g accurately? Is it necessary to measure 1.0 mL
of accurately?
(b) Write a balanced reaction between and sulfite.
(c) Find the concentration of sulfite in the wine. Express your answer in mol/L and in per liter.
(d) t test. Another wine was found to contain with a standard deviation of for three determinations by the iodimetric method. A spectrophotometric method gaverole="math" localid="1663607422230" in three determinations. Are these results significantly different at the 95 % confidence level?
A sample containing was treated with sodium oxalate to precipitate which was washed, dissolved in acid and titrated with 18.04mL of . Write the titration reaction and find in the unknown.
Would indigo tetrasulfonate be a suitable redox indicator for the titration of with in 1MHCI? (Hint: The potential at the equivalence point must be between the potentials for each redox couple.)
A 3.026-g portion of a copper(II) salt was dissolved in a 250-mL volumetric flask. A 50.0-mL aliquot was analyzed by adding of KI and titrating the liberated iodine with 23.33mL of Find the weight percent of Cu in the salt. Should starch indicator be added to this titration at the beginning or just before the end point?
What is a Jones reductor and what is it used for?
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