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State two ways to make standard triiodide solution.

Short Answer

Expert verified

To make standard triiodide solution is to mix together KIO3andKIandand then add a strong acid such as HCIorH2SO4.

Step by step solution

01

Definition of Iodine.

  • Iodine is a chemical element with atomic number 53and the symbol I.

  • At typical conditions, it exists as a semi-lustrous, non-metallic solid that melts to produce a deep violet liquid at114Cand boils to form a violet gas at 184C

  • Iodine is found in a variety of oxidation states, including iodideI, iodateIO3-, and periodate anions.

  • It is the least common of the stable halogens, occupying the sixty-first position in the periodic table.

  • It is the heaviest nutrient in terms of necessary minerals.

02

To determine the ways to make standard triiodide solutions

One way to make standard triiodide solution is to mix together KIO3andKIandthen add a strong acid such as HCIorH2SO4.

Triiodide is formed by a reverse disproportionation

IO3-8I+6H3I3+3H2O

Thiosulfate can also be used for standardization of triiodide.

It reacts with triiodide and iodide and tetrathionate ions are formed:

2S2O32+I3-3I-+S4O62

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Most popular questions from this chapter

Some people have an allergic reaction to the food preservative sulfite (SO32-), which can be measured by instrumental methods 37 or by a redox titration: To 50.0mL of wine were added 50.0mL of solution containing (0.8043gKIO3+6.0gKI)/100mL . Acidification with 1.0 mL of 6.0MH2SO4 quantitatively converted role="math" localid="1663606948648" lO3 into l3 . The l3 reacted with SO32- to generate role="math" localid="1663607055826" SO42- , leaving excess l3 in solution. The excess l3 required of 12.86mLof0.04818MNa2S2O3to reach a starch end point.

(a) Write the reaction that occurs when H2SO4is added to KIO3+ KI and explain why 6.0 gKI were added to the stock solution. Is it necessary to measure out 6.0 g accurately? Is it necessary to measure 1.0 mL
ofH2SO4 accurately?

(b) Write a balanced reaction betweenl3 and sulfite.

(c) Find the concentration of sulfite in the wine. Express your answer in mol/L and inmgSO32- per liter.

(d) t test. Another wine was found to contain 277.7mgSO32-/Lwith a standard deviation of 2.2mg/Lfor three determinations by the iodimetric method. A spectrophotometric method gaverole="math" localid="1663607422230" 273.22.1mg/L in three determinations. Are these results significantly different at the 95 % confidence level?

A sample containing La3+ was treated with sodium oxalate to precipitateLa2(C2O4)3 which was washed, dissolved in acid and titrated with 18.04mL of0.006363MKMnO4 . Write the titration reaction and find[La3+] in the unknown.

Would indigo tetrasulfonate be a suitable redox indicator for the titration of Fe(CN)64-with TI3+in 1MHCI? (Hint: The potential at the equivalence point must be between the potentials for each redox couple.)

A 3.026-g portion of a copper(II) salt was dissolved in a 250-mL volumetric flask. A 50.0-mL aliquot was analyzed by adding of KI and titrating the liberated iodine with 23.33mL of 0.04668MNa2S2O3Find the weight percent of Cu in the salt. Should starch indicator be added to this titration at the beginning or just before the end point?

What is a Jones reductor and what is it used for?

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