Chapter 16: Q23P (page 392)
State two ways to make standard triiodide solution.
Short Answer
To make standard triiodide solution is to mix together and then add a strong acid such as .
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Chapter 16: Q23P (page 392)
State two ways to make standard triiodide solution.
To make standard triiodide solution is to mix together and then add a strong acid such as .
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Would indigo tetrasulfonate be a suitable redox indicator for the titration of with in 1MHCI? (Hint: The potential at the equivalence point must be between the potentials for each redox couple.)
Aqueous glycerol solution weighing 100.0m gwas treated with 50.0 mL of 0.083 7 M in 4 MHCIat for15minto oxidize glycerol to formic acid.
Glycerol Formic acid
FM92.095
The excess required 12.11mL of 0.044 8 MFto reach a ferroin end point. Find wt%glycerol in the unknown.
Ascorbic acid (0.0100M)was added to 10.0mL of at pH 0.30, and the potential was monitored with Pt and saturated Ag | AgClelectrodes.
Dehydroascorbic acidrole="math" localid="1664865837362"
(a) Write a balanced equation for the titration reaction,
(b) Using for the role="math" localid="1664865912877" couple, calculate the cell voltage when 5.0,10.0 and 15.0 mL of ascorbic acid have been added. (Hint: Refer to the calculations in Demonstration 16 - 1.)
(a) Potassium iodate solution was prepared by dissolving 1.022gof in a 500 - mLvolumetric flask. Then 50.00mL of the solution were pipetted into a flask and treated with excess KI (2g) and acid ofHow many moles of are created by the reaction?
(b) The triiodide from part (a) reacted with 37.66 mL of solution. What is the concentration of the solution?
(c) A 1.223-g sample of solid containing ascorbic acid and inert ingredients was dissolved in dilute and treated with 2g of KI and 50.00mL of solution from part (a). Excess triiodide required14.22 mLofsolution from part (b). Find the weight percent of ascorbic acid (FM 176.13) in the unknown.
(d) Does it matter whether starch indicator is added at the beginning or near the end point in the titration in part (c)?
In which technique, iodimetry or iodometry, is starch indicator not added until just before the end point? Why?
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