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State two ways to make standard triiodide solution.

Short Answer

Expert verified

To make standard triiodide solution is to mix together KIO3andKIandand then add a strong acid such as HCIorH2SO4.

Step by step solution

01

Definition of Iodine.

  • Iodine is a chemical element with atomic number 53and the symbol I.

  • At typical conditions, it exists as a semi-lustrous, non-metallic solid that melts to produce a deep violet liquid at114Cand boils to form a violet gas at 184C

  • Iodine is found in a variety of oxidation states, including iodideI, iodateIO3-, and periodate anions.

  • It is the least common of the stable halogens, occupying the sixty-first position in the periodic table.

  • It is the heaviest nutrient in terms of necessary minerals.

02

To determine the ways to make standard triiodide solutions

One way to make standard triiodide solution is to mix together KIO3andKIandthen add a strong acid such as HCIorH2SO4.

Triiodide is formed by a reverse disproportionation

IO3-8I+6H3I3+3H2O

Thiosulfate can also be used for standardization of triiodide.

It reacts with triiodide and iodide and tetrathionate ions are formed:

2S2O32+I3-3I-+S4O62

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Most popular questions from this chapter

Would indigo tetrasulfonate be a suitable redox indicator for the titration of Fe(CN)64-with TI3+in 1MHCI? (Hint: The potential at the equivalence point must be between the potentials for each redox couple.)

Aqueous glycerol solution weighing 100.0m gwas treated with 50.0 mL of 0.083 7 M Ce4+in 4 MHCIO4at 60for15minto oxidize glycerol to formic acid.

CH2-CH-CH2|||OHOHOH HCO2H

Glycerol Formic acid

FM92.095

The excess Ce4+ required 12.11mL of 0.044 8 MFe2+to reach a ferroin end point. Find wt%glycerol in the unknown.

Ascorbic acid (0.0100M)was added to 10.0mL of 0.0200MFe3+at pH 0.30, and the potential was monitored with Pt and saturated Ag | AgClelectrodes.

Dehydroascorbic acidrole="math" localid="1664865837362" +2H++2e-ascorbicacid+H2OE=0.390V

(a) Write a balanced equation for the titration reaction,

(b) Using E0=0.767V for the role="math" localid="1664865912877" Fe3+Fe2+ couple, calculate the cell voltage when 5.0,10.0 and 15.0 mL of ascorbic acid have been added. (Hint: Refer to the calculations in Demonstration 16 - 1.)

(a) Potassium iodate solution was prepared by dissolving 1.022gof KIO3(FM214.00)in a 500 - mLvolumetric flask. Then 50.00mL of the solution were pipetted into a flask and treated with excess KI (2g) and acid (10mLof0.5MH2SO4) ofHow many moles of fl3- are created by the reaction?

(b) The triiodide from part (a) reacted with 37.66 mL of Na2S2O3solution. What is the concentration of the Na2S2O3 solution?

(c) A 1.223-g sample of solid containing ascorbic acid and inert ingredients was dissolved in dilute H2SO4 and treated with 2g of KI and 50.00mL of KIO3solution from part (a). Excess triiodide required14.22 mLofNa2S2O3solution from part (b). Find the weight percent of ascorbic acid (FM 176.13) in the unknown.

(d) Does it matter whether starch indicator is added at the beginning or near the end point in the titration in part (c)?

In which technique, iodimetry or iodometry, is starch indicator not added until just before the end point? Why?

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