Chapter 7: Q33P (page 314)
What is each compound’s systematic name?
Short Answer
a. 5-bromo-2-hexyne
b. 5-methyl-2-octyne
c. 5,5-dimethyl-2-hexyne
d. 6-chloro-2-methyl-3-heptyne
e. 1,5-cyclooctadiene
f. 1,6-dimethyl-1,3-cyclohexadiene
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Chapter 7: Q33P (page 314)
What is each compound’s systematic name?
a. 5-bromo-2-hexyne
b. 5-methyl-2-octyne
c. 5,5-dimethyl-2-hexyne
d. 6-chloro-2-methyl-3-heptyne
e. 1,5-cyclooctadiene
f. 1,6-dimethyl-1,3-cyclohexadiene
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Which alkyne would be the best one to use for the synthesis of each of the following ketones?

Why does cis-2-butene have a higher boiling point than trans-2-butene?
Which of the following bases can remove a proton from a terminal alkyne in a reaction that favors products?

Draw the structures and give the common and systematic names for the seven alkynes with molecular formula C6H10.
Drawing on what you know about the stereochemistry of alkene addition reactions:
a. Write the mechanism for the reaction of 2-butyne with one equivalent of Br2.
b. Predict the configuration of the product of the reaction.
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