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Chapter 9: Q22P (page 415)

What is the major elimination product obtained from the reaction of each of the following alkyl halides with hydroxide ions?

Short Answer

Expert verified

a)

b)

c)

Step by step solution

01

How SN1 reaction proceed

1. It is a two step reaction.

2. In this carbocation is formed.

3. In this negative ion will attack from the side where there is less number of bulkier groups.

4. As the carbocation intermediate is formed so the stability order 3掳 carbocation>2掳 carbocation>1掳 carbocation

02

Final answer

a) Here OH will attach on the place of Iodine but then OH and H from adjacent carbon will release and form double bond.

b) Here OH will attach on the place of Bromine but then OH and H from adjacent carbon will release and form double bond.

c) Here OH will attach on the place of Bromine but due to methyl shift OH will go to adjacent carbon then OH and H from adjacent carbon will release and form double bond.

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Most popular questions from this chapter

How will the rate of each of the following SN2reactions change if it is carried out in a more polar solvent?

What is the product of the reaction of bromoethane with each of the following nucleophiles?

Which reactant in each of the following pairs undergoes an elimination reaction more rapidly? Explain your choice.

Draw the products of each of the following SN2/E2 reactions. If the products can exist as stereoisomers, show which stereoisomers are formed.

a.(3S,4S)-3-bromo-4-methylhexane + CH3O-

b.(3R,4R)-3-bromo-4-methylhexane + CH3O-

c.(3S,4R)-3-bromo-4-methylhexane + CH3O-

d.(3R,4S)-3-bromo-4-methylhexane + CH3O-

Methoxychlor is an insecticide that was intended to take DDT鈥檚 place because it is not as soluble in fatty tissues and is more readily biodegradable. It, too, can accumulate in the environment, however, so its use was also banned鈥攊n 2002 in the European Union and in 2003 in the United States. Why is methoxychlor less soluble in fatty tissues than DDT?
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