Chapter 18: Q53P (page 915)
If anisole is allowed to sit in that contains a small amount of, what products are formed?
Short Answer
The product formed when anisole is placed in is,

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Chapter 18: Q53P (page 915)
If anisole is allowed to sit in that contains a small amount of, what products are formed?
The product formed when anisole is placed in is,

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Propose a mechanism for each of the following reactions:
a.

b.

Show how the following compounds can be synthesized from benzene:
a)

b)

c)

Question: Which is a more stable intermediate in each pair?
a.

b.

Question: Draw a structure for each of the following: a. 2-phenylhexane
b. benzyl alcohol
c. 3-benzylpentane
d. bromomethylbenzene
Question: The pKa values of a few ortho-, meta-, and para-substituted benzoic acids are shown below:

The relative pKa values depend on the substituent. For chloro-substituted benzoic acids, the ortho isomer is the most acidic and the para isomer is the least
acidic; for nitro-substituted benzoic acids, the ortho isomer is the most acidic and the meta isomer is the least acidic; and for amino-substituted benzoic acids, the meta isomer is the most acidic and the ortho isomer is the least acidic. Explain these relative acidities.
a. Cl: ortho > meta > para
b. NO2: ortho > para > meta
c. NH2: meta > para > ortho
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