Chapter 18: Q16P (page 893)
Draw the resonance contributors for:
a. benzaldehyde
b. chlorobenzene.
Short Answer
a)

b)

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Chapter 18: Q16P (page 893)
Draw the resonance contributors for:
a. benzaldehyde
b. chlorobenzene.
a)

b)

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Show how the following compounds can be prepared from the given starting materials. You can use any necessary organic or inorganic reagents.
a.

b.

Question: Propose a mechanism for each of the following reactions:
a.)

b.)

a. Ketoprofen, like ibuprofen, is an anti-inflammatory analgesic. How can ketoprofen be synthesised from the given starting material?
Ketoprofen
b. ketoprofen and ibuprofen both have a propanoic acid substituent. Explain why the identical subunits are synthesised in different ways.
What products are obtained from the reaction of the following compounds with H2CrO4+ 螖?
a.

b.

c.
c. 
Question: p-fluoronitrobenzene is more reactive toward hydroxide ion than is p-chloronitrobenzene. What does this tell you about the rate-determining step fornucleophilic aromatic substitution?
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