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Chapter 10: Q21P (page 472)

What alcohol would you treat with phosphorus oxychloride and pyridine to form each of the following alkenes?

Short Answer

Expert verified

1. It is a two step reaction.

2.In this carbocation is formed.

3. In this negative ion will attack from the side where there is less number of bulkier groups.

4. As the carbocation intermediate is formed so the stability order 3掳 carbocation>2掳 carbocation>1掳 carbocation

5. As the carboanion intermediate is formed so the stability order 1掳 carboanion>2掳 carboanion>3掳 carboanion

Step by step solution

01

How SN1 reaction proceed

1. It is a two step reaction.

2.In this carbocation is formed.

3. In this negative ion will attack from the side where there is less number of bulkier groups.

4. As the carbocation intermediate is formed so the stability order 3掳 carbocation>2掳 carbocation>1掳 carbocation

5. As the carboanion intermediate is formed so the stability order 1掳 carboanion>2掳 carboanion>3掳 carboanion

02

Final answer

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