Chapter 14: Q31P (page 644)
Identify the compound with a molecular formula that gives the IR and NMR spectra shown here.

Short Answer
The structure of the compound is as follows;

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Chapter 14: Q31P (page 644)
Identify the compound with a molecular formula that gives the IR and NMR spectra shown here.

The structure of the compound is as follows;

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Identify each of the following compounds from its molecular formula and its 13C NMR spectrum:
a.C4H10O

b.C6H12O

Describe the proton-coupled 13C NMR spectra for compounds 1, 3, and 5 indicating the relative positions of the signals.



Which has a greater chemical shift for the proton, the proton H1NMR spectrum of pure ethanol or the proton H1NMR spectrum of ethanol dissolved in CH2Cl2.
Dr. N. M. Arr was called in to help analyze the 1 H NMR spectrum of a mixture of compounds known to contain only C, H, and Br. The mixture showed two singlets-one at 1.8 ppm and the other at 2.7 ppm-with relative integrals of 1: 6, respectively. Dr. Arr determined that the spectrum was that of a mixture of bromomethane and 2-Bromo-2-methylpropane. What was the ratio of bromomethane to 2-Bromo-2-methylpropane in the mixture?
a. Which proton or set of protons in each of the following compounds is the least shielded?
b. Which proton or set of protons in each compound is the most shielded?

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