Chapter 8: Q37 P (page 355)
What are the major 1,2- and 1,4-addition products of the following reactions? For each reaction, indicate the kinetic and the thermodynamic product.

Short Answer
a.

b.

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Chapter 8: Q37 P (page 355)
What are the major 1,2- and 1,4-addition products of the following reactions? For each reaction, indicate the kinetic and the thermodynamic product.

a.

b.

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a. Which oxygen atom has the greater electron density?

b. Which compound has the greater electron density on its nitrogen atom?

c. Which compound has the greater electron density on its oxygen atom?

What products would be obtained from the reaction of 1,3,5-hexatriene with one equivalent of HBr? Disregard stereoisomers.
Draw the products obtained from the reaction of one equivalent of HBr with one equivalent of 1,3,5-hexatriene.
a. Which product(s) will predominate if the reaction is under kinetic control?
b. Which product(s) will predominate if the reaction is under thermodynamic control?
Protonated cyclohexylamine has aKa=1×10−11. Using the same sequence of steps as in Problem 94 , determine which is a stronger base, cyclohexylamine or aniline.

Draw the major products obtained from the reaction of one equivalent of HBr with the following compounds. For each reaction, indicate the kinetic product and the thermodynamic product.

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